4-Phenylazophenacyl Bromide

Base Information

• Chemical Name: 4-Phenylazophenacyl Bromide
• CAS No.: 62625-24-5
• Deprecated CAS: 125906-59-4
• Molecular Formula: C14H11BrN2O
• Molecular Weight: 303.1539
• Hs Code.: 2927000090
• European Community (EC) Number: 677-949-8
• DSSTox Substance ID: DTXSID0069595
• Nikkaji Number: J150.207G
• Mol file: 62625-24-5.mol

Synonyms:4-Phenylazophenacyl Bromide;62625-24-5;2-Bromo-1-(4-(phenyldiazenyl)phenyl)ethanone;2-bromo-1-(4-phenyldiazenylphenyl)ethanone;Ethanone, 2-bromo-1-(4-(phenylazo)phenyl)-;Ethanone, 2-bromo-1-[4-(phenylazo)phenyl]-;C14H11BrN2O;Ethanone, 2-bromo-1-(4-(2-phenyldiazenyl)phenyl)-;p-Phenylazophenacylbromid;4-(Bromoacetyl)azobenzene;SCHEMBL571677;DTXSID0069595;2-Bromo-4'-phenylazoacetophenone;MFCD00017875;AKOS025295559;AS-79121;B0634;FT-0640839;T71144;2-Bromo-1-[4-(phenyldiazenyl)phenyl]ethanone #;A833895;(E)-2-bromo-1-(4-(phenyldiazenyl)phenyl)ethanone

Chemical Property of 4-Phenylazophenacyl Bromide

Chemical Property:

• Melting Point: 104oC
• Boiling Point: 427°Cat760mmHg
• Flash Point: 212°C
• PSA: 41.79000
• Density: 1.37g/cm³
• LogP: 4.67960
• XLogP3: 4.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 4
• Exact Mass: 302.00548
• Heavy Atom Count: 18
• Complexity: 292

Purity/Quality:

97% ^*data from raw suppliers

4-Phenylazophenacyl Bromide >98.0%(T) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)N=NC2=CC=C(C=C2)C(=O)CBr

Technology Process of 4-Phenylazophenacyl Bromide

There total 3 articles about 4-Phenylazophenacyl Bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-acetoazobenzene (4827-16-1) → 2-bromo-1-(4-phenylazo-phenyl)-ethanone (62625-24-5)

Guidance literature:

With bromine; acetic acid; at 75 ℃;

Reference yield:

2-diazo-1-(4-phenylazo-phenyl)-ethanone (92061-10-4) → 2-bromo-1-(4-phenylazo-phenyl)-ethanone (62625-24-5)

Guidance literature:

With chloroform; hydrogen bromide;

Reference yield:

4-phenylazobenzoyl chloride (104-24-5) → 2-bromo-1-(4-phenylazo-phenyl)-ethanone (62625-24-5)

Guidance literature:

Multi-step reaction with 2 steps

1: diethyl ether

2: HBr; CHCl₃

With diethyl ether; chloroform; hydrogen bromide;

upstream raw materials:

2-diazo-1-(4-phenylazo-phenyl)-ethanone

4-acetoazobenzene

4-phenylazobenzoyl chloride

Downstream raw materials:

(S)-2-Amino-succinic acid bis-[2-oxo-2-(4-phenylazo-phenyl)-ethyl] ester; hydrobromide

(S)-2,6-Diamino-hexanoic acid 2-oxo-2-(4-phenylazo-phenyl)-ethyl ester; hydrobromide

(2S,3S)-2-Amino-3-methyl-pentanoic acid 2-oxo-2-(4-phenylazo-phenyl)-ethyl ester; hydrobromide

(S)-Pyrrolidine-2-carboxylic acid 2-oxo-2-(4-phenylazo-phenyl)-ethyl ester; hydrobromide