Phosphine, 1,11-undecanediylbis[diphenyl-

Base Information

Chemical Name:Phosphine, 1,11-undecanediylbis[diphenyl-
CAS No.:82195-41-3
Molecular Formula:C35H42P2
Molecular Weight:524.666
Hs Code.:
DSSTox Substance ID:DTXSID20478005
Nikkaji Number:J2.117.776H

Synonyms:Phosphine, 1,11-undecanediylbis[diphenyl-;82195-41-3;DTXSID20478005

Suppliers and Price of Phosphine, 1,11-undecanediylbis[diphenyl-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of Phosphine, 1,11-undecanediylbis[diphenyl-

Chemical Property:

XLogP3:10
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:16
Exact Mass:524.27617534
Heavy Atom Count:37
Complexity:454

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)P(CCCCCCCCCCCP(C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4

Technology Process of Phosphine, 1,11-undecanediylbis[diphenyl-

There total 1 articles about Phosphine, 1,11-undecanediylbis[diphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 16696-65-4
1,11-dibromoundecane

: 15475-27-1,4346-39-8
potassium diphenylphosphine

: 82195-41-3
(C₆H₅)2P(CH₂)11P(C₆H₅)2

Guidance literature:: In tetrahydrofuran;

Reference yield: 80.0%

: 464896-38-6,464896-36-4
trans,trans-(C₆F₅)(Ph₂P-(CH₂)14PPh₂)Pt-(C₂)4Pt-(Ph₂P(CH₂)14Ph₂P-)(C₆F₅)

: 82195-41-3
(C₆H₅)2P(CH₂)11P(C₆H₅)2

: 464896-32-0
trans,trans-(C₆F₅)(Ph₂P-(CH₂)11PPh₂Pt-(C₂)4Pt-(Ph₂P(CH₂)11P-Ph₂)(C₆F₅)

Guidance literature:: In dichloromethane; a Schlenk flack was charged with Pt-complex and CH2Cl2, a soln. of diphosphine in CH2Cl2 was passed through a silica gel pad with stirring, 2 h of stirring; the solvent was removed by oil pump vac., ethanol was added, filtered, washed with ethanol, dried by oil pump vac.;
DOI:10.1021/ja0716103

Reference yield: 80.0%

: trans,trans-(C₆F₅)((p-tolyl)3P)2Pt(CC)4Pt(P(p-tolyl)3)2(C₆F₅)

: 82195-41-3
(C₆H₅)2P(CH₂)11P(C₆H₅)2

: 464896-32-0
trans,trans-(C₆F₅)(Ph₂P-(CH₂)11PPh₂Pt-(C₂)4Pt-(Ph₂P(CH₂)11P-Ph₂)(C₆F₅)

Guidance literature:: In dichloromethane; treated with phosphane in moderate dilute conditions;
DOI:10.1002/1521-3773(20020603)41:11<1871::AID-ANIE1871>3.0.CO;2-V