Benzene, 1-methyl-4-[(3-methyl-1,2-butadienyl)sulfonyl]-

Base Information

Chemical Name:Benzene, 1-methyl-4-[(3-methyl-1,2-butadienyl)sulfonyl]-
CAS No.:82352-39-4
Molecular Formula:C12H14O2S
Molecular Weight:222.308
Hs Code.:
DSSTox Substance ID:DTXSID10448853
Nikkaji Number:J2.414.714B

Synonyms:82352-39-4;Benzene, 1-methyl-4-[(3-methyl-1,2-butadienyl)sulfonyl]-;DTXSID10448853;1-Tosyl-3-methyl-1,2-butadiene

Suppliers and Price of Benzene, 1-methyl-4-[(3-methyl-1,2-butadienyl)sulfonyl]-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Benzene, 1-methyl-4-[(3-methyl-1,2-butadienyl)sulfonyl]-

Chemical Property:

XLogP3:2.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:222.07145086
Heavy Atom Count:15
Complexity:355

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC=C(C=C1)S(=O)(=O)C=C=C(C)C

Technology Process of Benzene, 1-methyl-4-[(3-methyl-1,2-butadienyl)sulfonyl]-

There total 7 articles about Benzene, 1-methyl-4-[(3-methyl-1,2-butadienyl)sulfonyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 109787-25-9
1,1-dimethyl-2-propynyl 4-methylbenzenesulfinate

: 82352-39-4
1-<<3-methyl-1,2-Butadienyl>sulfonyl>-4-methylbenzene

Guidance literature:: With Ag¹-USY zeolite; In dichloromethane; at 20 ℃; for 4h; Solvent; Reagent/catalyst; Inert atmosphere; Green chemistry;
DOI:10.1002/adsc.201400978

Reference yield: 89.0%

: 1

: 82352-39-4
1-<<3-methyl-1,2-Butadienyl>sulfonyl>-4-methylbenzene

Guidance literature:: With silver hexafluoroantimonate; In dichloromethane; at 20 ℃; for 0.0333333h; Inert atmosphere;
DOI:10.1002/adsc.201600986

Reference yield:

: 10439-23-3
4-methylbenzenesulfinyl chloride

: 82352-39-4
1-<<3-methyl-1,2-Butadienyl>sulfonyl>-4-methylbenzene

Guidance literature:: Multi-step reaction with 2 steps

1: 91 percent / Et₃N / CH₂Cl₂ / 1.) -78 deg C, 2 h, 2.) 0 deg C, 1 h

2: 67 percent / 2,6-lutidine / acetonitrile / 6 h / Heating

With 2,6-dimethylpyridine; triethylamine; In dichloromethane; acetonitrile;
DOI:10.1002/recl.19951140203