5-Hexenoic acid,4-methoxy-2-(methoxymethyl- ene)-3-methyl-6-phenyl-,methyl ester,(2E,3R,4S,5E)-

Base Information

Chemical Name:5-Hexenoic acid,4-methoxy-2-(methoxymethyl- ene)-3-methyl-6-phenyl-,methyl ester,(2E,3R,4S,5E)-
CAS No.:90695-50-4
Molecular Formula:C₁₇H₂₂O₄
Molecular Weight:290.359
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 5-Hexenoic acid,4-methoxy-2-(methoxymethyl- ene)-3-methyl-6-phenyl-,methyl ester,(2E,3R,4S,5E)-

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 5-Hexenoic acid,4-methoxy-2-(methoxymethyl- ene)-3-methyl-6-phenyl-,methyl ester,(2E,3R,4S,5E)-

There total 79 articles about 5-Hexenoic acid,4-methoxy-2-(methoxymethyl- ene)-3-methyl-6-phenyl-,methyl ester,(2E,3R,4S,5E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₁₆H₂₀O₄

: 77-78-1
dimethyl sulfate

: 90695-50-4
(2E,3R,4S,5E)-methyl 4-methoxy-2-(methoxymethylene)-3-methyl-6-phenylhex-5-enoate

Guidance literature:: With potassium carbonate; In acetone; at 20 ℃; for 12h; Inert atmosphere;
DOI:10.1016/j.tetasy.2017.06.002

Reference yield:

: 88088-55-5,109864-29-1,109864-30-4,109864-31-5
(E)-(3R^*,4S^*)-4-methoxy-3-methyl-6-phenylhex-5-enol

: 73341-71-6,82444-24-4,82444-25-5,88644-09-1,90695-49-1,90695-50-4
oudemansin A

Guidance literature:: Multi-step reaction with 2 steps

1: 100 percent / 8 N Jones reagent / acetone / 2 h

2: 1.) t-BuLi, 2.) K₂CO₃ / 2.) acetone

With jones reagent; tert.-butyl lithium; potassium carbonate; In acetone;
DOI:10.1021/jo00228a028

Reference yield:

: 88088-54-4,106315-62-2,109864-19-9,109864-32-6
(E)-(3S^*,4R^*)-3-methoxy-4-methyl-1-phenylhexa-1,5-diene

: 73341-71-6,82444-24-4,82444-25-5,88644-09-1,90695-49-1,90695-50-4
oudemansin A

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) 9-BBN, 2.) 15percent aq. NaOH, 30percent aq. H₂O₂ / 1.) THF, from 0 deg C to RT, overnight, 2.) THF, EtOH, 4 h

2: 100 percent / 8 N Jones reagent / acetone / 2 h

3: 1.) t-BuLi, 2.) K₂CO₃ / 2.) acetone

With sodium hydroxide; 9-borabicyclo[3.3.1]nonane dimer; jones reagent; dihydrogen peroxide; tert.-butyl lithium; potassium carbonate; In acetone;
DOI:10.1021/jo00228a028