5,13,15-Hexadecatrienal, 3,9-bis[[(1,1-dimethylethyl)dimethylsilyl]oxy]-11-[(4-methoxyphenyl)meth oxy]-2,4,6,8,10,12-hexamethyl-, (2R,3R,4S,5Z,8S,9R,10R,11S,12S,13Z)-

Base Information Edit

Chemical Name:5,13,15-Hexadecatrienal, 3,9-bis[[(1,1-dimethylethyl)dimethylsilyl]oxy]-11-[(4-methoxyphenyl)meth oxy]-2,4,6,8,10,12-hexamethyl-, (2R,3R,4S,5Z,8S,9R,10R,11S,12S,13Z)-
CAS No.:827017-66-3
Molecular Formula:C42H74O5Si2
Molecular Weight:715.218
Hs Code.:
Mol file:827017-66-3.mol

5,13,15-Hexadecatrienal,
3,9-bis[[(1,1-dimethylethyl)dimethylsilyl]oxy]-11-[(4-methoxyphenyl)meth
oxy]-2,4,6,8,10,12-hexamethyl-,
(2R,3R,4S,5Z,8S,9R,10R,11S,12S,13Z)-

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 5,13,15-Hexadecatrienal, 3,9-bis[[(1,1-dimethylethyl)dimethylsilyl]oxy]-11-[(4-methoxyphenyl)meth oxy]-2,4,6,8,10,12-hexamethyl-, (2R,3R,4S,5Z,8S,9R,10R,11S,12S,13Z)- Edit

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MSDS Files:: SDS file from LookChem

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Technology Process of 5,13,15-Hexadecatrienal, 3,9-bis[[(1,1-dimethylethyl)dimethylsilyl]oxy]-11-[(4-methoxyphenyl)meth oxy]-2,4,6,8,10,12-hexamethyl-, (2R,3R,4S,5Z,8S,9R,10R,11S,12S,13Z)-

There total 2 articles about 5,13,15-Hexadecatrienal, 3,9-bis[[(1,1-dimethylethyl)dimethylsilyl]oxy]-11-[(4-methoxyphenyl)meth oxy]-2,4,6,8,10,12-hexamethyl-, (2R,3R,4S,5Z,8S,9R,10R,11S,12S,13Z)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 252342-46-4
(5Z,13Z)-(2S,3R,4S,8S,9R,10R,11S,12S)-3,9-Bis-(tert-butyl-dimethyl-silanyloxy)-11-(4-methoxy-benzyloxy)-2,4,6,8,10,12-hexamethyl-hexadeca-5,13,15-trien-1-ol

: 827017-66-3
3,9-bis-(tert-butyl-dimethyl-silanyloxy)-11-(4-methoxy-benzyloxy)-2,4,6,8,10,12-hexamethyl-hexadeca-5,13,15-trienal

Guidance literature:: With [bis(acetoxy)iodo]benzene; 2,2,6,6-tetramethyl-piperidine-N-oxyl; In dichloromethane;
DOI:10.1039/b615122a

Reference yield:

: 256920-81-7
1-[(5Z,13Z)-(2S,3R,4S,8S,9R,10R,11S,12S)-11-(4-methoxybenzoxy)-3,9-bis(tert-butyldimethylsilanyloxy)-2,4,6,8,10,12-hexamethylhexadeca-5,13,15-trienyloxymethyl]-4-methoxybenzene

: 827017-66-3
3,9-bis-(tert-butyl-dimethyl-silanyloxy)-11-(4-methoxy-benzyloxy)-2,4,6,8,10,12-hexamethyl-hexadeca-5,13,15-trienal

Guidance literature:: Multi-step reaction with 2 steps

1: 90 percent / BCl₃*DMS / CH₂Cl₂

2: 99 percent / PhI(OAc)2 / TEMPO / CH₂Cl₂

With [bis(acetoxy)iodo]benzene; boron trichloride - methyl sulfide complex; 2,2,6,6-tetramethyl-piperidine-N-oxyl; In dichloromethane;
DOI:10.1039/b615122a