(2R,3R,5S,6S)-5,6-Bis(azidomethyl)-2,3-dimethoxy-2,3-dimethyl-1,4-dioxane

Base Information

Chemical Name:(2R,3R,5S,6S)-5,6-Bis(azidomethyl)-2,3-dimethoxy-2,3-dimethyl-1,4-dioxane
CAS No.:832117-79-0
Molecular Formula:C₁₀H₁₈N₆O₄
Molecular Weight:286.291
Hs Code.:
European Community (EC) Number:691-464-9
DSSTox Substance ID:DTXSID70693721
Wikidata:Q82622749
Mol file:832117-79-0.mol

Synonyms:(2R,3R,5S,6S)-5,6-Bis(azidomethyl)-2,3-dimethoxy-2,3-dimethyl-1,4-dioxane;832117-79-0;B3693;SCHEMBL24437493;DTXSID70693721;D89030;(2R,3R,5S,6S)-5,6-Bis(azidomethyl)-2,3-dimethoxy-2,3-dimethyl-1,4-dioxane, 97%

Suppliers and Price of (2R,3R,5S,6S)-5,6-Bis(azidomethyl)-2,3-dimethoxy-2,3-dimethyl-1,4-dioxane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TCI Chemical
(2R,3R,5S,6S)-5,6-Bis(azidomethyl)-2,3-dimethoxy-2,3-dimethyl-1,4-dioxane >97.0%(GC)
100mg
$ 95.00

Biosynth Carbosynth
(2R,3R,5S,6S)-5,6-Bis(azidoMethyl)-2,3-diMethoxy-2,3-diMethyl-1,4-dioxane
100 mg
$ 200.00

Biosynth Carbosynth
(2R,3R,5S,6S)-5,6-Bis(azidoMethyl)-2,3-diMethoxy-2,3-diMethyl-1,4-dioxane
50 mg
$ 125.00

Biosynth Carbosynth
(2R,3R,5S,6S)-5,6-Bis(azidoMethyl)-2,3-diMethoxy-2,3-diMethyl-1,4-dioxane
1 g
$ 1400.00

Biosynth Carbosynth
(2R,3R,5S,6S)-5,6-Bis(azidoMethyl)-2,3-diMethoxy-2,3-diMethyl-1,4-dioxane
500 mg
$ 800.00

Biosynth Carbosynth
(2R,3R,5S,6S)-5,6-Bis(azidoMethyl)-2,3-diMethoxy-2,3-diMethyl-1,4-dioxane
250 mg
$ 450.00

AK Scientific
(2R,3R,5S,6S)-5,6-Bis(azidomethyl)-2,3-dimethoxy-2,3-dimethyl-1,4-dioxane
100mg
$ 260.00

Total 6 raw suppliers

Chemical Property of (2R,3R,5S,6S)-5,6-Bis(azidomethyl)-2,3-dimethoxy-2,3-dimethyl-1,4-dioxane

Chemical Property:

Melting Point:80.0 to 84.0 °C
PSA：136.42000
LogP:1.02172
XLogP3:2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:8
Rotatable Bond Count:6
Exact Mass:286.13895308
Heavy Atom Count:20
Complexity:396

Purity/Quality:

98%,99%, ^*data from raw suppliers

(2R,3R,5S,6S)-5,6-Bis(azidomethyl)-2,3-dimethoxy-2,3-dimethyl-1,4-dioxane >97.0%(GC) ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1(C(OC(C(O1)CN=[N+]=[N-])CN=[N+]=[N-])(C)OC)OC
Isomeric SMILES:C[C@@]1([C@](O[C@H]([C@@H](O1)CN=[N+]=[N-])CN=[N+]=[N-])(C)OC)OC

Technology Process of (2R,3R,5S,6S)-5,6-Bis(azidomethyl)-2,3-dimethoxy-2,3-dimethyl-1,4-dioxane

There total 3 articles about (2R,3R,5S,6S)-5,6-Bis(azidomethyl)-2,3-dimethoxy-2,3-dimethyl-1,4-dioxane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.0%

: 340039-00-1
(2R,3R,5S,6S)-2,3-dimethoxy-2,3-dimethyl-5,6-bis(((methanesulfonyl)oxy)methyl)[1,4]dioxane

: 832117-79-0
(2R,3R,5S,6S)-5,6-bis(azidomethyl)-2,3-dimethoxy-2,3-dimethyl[1,4]dioxane

: 1031246-20-4
[(2R,3R,5S,6S)-5-azidomethyl-2,3-dimethoxy-2,3-dimethyl-1,4-dioxan-6-yl]methyl methanesulfonate

Guidance literature:: With sodium azide; In acetonitrile; Heating;
DOI:10.1080/00397910801916520

Reference yield:

: 173371-55-6
(2S,3S,5R,6R)-2,3-bis(hydroxymethyl)-5,6-dimethoxy-5,6-dimethyl<1,4>dioxane

: 832117-79-0
(2R,3R,5S,6S)-5,6-bis(azidomethyl)-2,3-dimethoxy-2,3-dimethyl[1,4]dioxane

Guidance literature:: (2S,3S,5R,6R)-2,3-bis(hydroxymethyl)-5,6-dimethoxy-5,6-dimethyl<1,4>dioxane; With methanesulfonyl chloride; triethylamine; In tetrahydrofuran; at 0 - 25 ℃; for 1h;

With sodium azide; In DMF (N,N-dimethyl-formamide); at 60 ℃; for 14h;