1,8-Bis(diphenylphosphino)-9,10-dihydro-9,10-ethanoanthracene

Base Information

Chemical Name:1,8-Bis(diphenylphosphino)-9,10-dihydro-9,10-ethanoanthracene
CAS No.:832673-32-2
Molecular Formula:C40H32P2
Molecular Weight:574.642
Hs Code.:
DSSTox Substance ID:DTXSID40476361
Nikkaji Number:J2.364.497E,J2.963.157C

Synonyms:1,8-bis(diphenylphosphino)-9,10-dihydro-9,10-ethanoanthracene;832673-32-2;SCHEMBL6317937;DTXSID40476361;OGPMTQBIWRYJNE-UHFFFAOYSA-N

Suppliers and Price of 1,8-Bis(diphenylphosphino)-9,10-dihydro-9,10-ethanoanthracene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of 1,8-Bis(diphenylphosphino)-9,10-dihydro-9,10-ethanoanthracene

Chemical Property:

XLogP3:9.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:6
Exact Mass:574.19792502
Heavy Atom Count:42
Complexity:744

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1CC2C3=C(C1C4=C2C(=CC=C4)P(C5=CC=CC=C5)C6=CC=CC=C6)C=CC=C3P(C7=CC=CC=C7)C8=CC=CC=C8

Technology Process of 1,8-Bis(diphenylphosphino)-9,10-dihydro-9,10-ethanoanthracene

There total 1 articles about 1,8-Bis(diphenylphosphino)-9,10-dihydro-9,10-ethanoanthracene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: 38366-40-4
1,8-dichloro-9,10-ethano-9,10-dihydroanthracene

: 1079-66-9,74391-44-9
chloro-diphenylphosphine

: 832673-32-2
1,8-bis(diphenylphosphino)-9,10-ethano-9,10-dihydroanthracene

Guidance literature:: 1,8-dichloro-9,10-ethano-9,10-dihydroanthracene; With sodium; lithium; In tetrahydrofuran; at -78 ℃; for 6h; Inert atmosphere;

chloro-diphenylphosphine; In tetrahydrofuran; at -78 - 20 ℃; Inert atmosphere;
DOI:10.1021/om200164f

Reference yield: 63.0%

: 1295-35-8
bis(1,5-cyclooctadiene)nickel ⁽⁰⁾

: 563-52-0,35729-37-4
2-chloro-3-butene

: 832673-32-2
1,8-bis(diphenylphosphino)-9,10-ethano-9,10-dihydroanthracene

: 108-88-3,15644-74-3,16713-13-6
toluene

: 1296889-06-9
(1,8-bis(diphenylphosphino)-9,10-ethano-9,10-dihydroanthracene)Ni(η3-methallyl)Cl*(toluene)

Guidance literature:: In toluene; byproducts: 1,5-cyclooctadiene; under Ar; mixt. of Ni complex and phosphine (molar ratio 1:1) dissolved in toluene; stirred at room temp. for 5 min; CH2CHCH(Cl)CH3 added; stirred at room temp. overnight; filtered; ppt. washed with n-pentane; elem. anal.;
DOI:10.1021/om200164f