8-Tridecenal, 5,11-bis[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3-[(4-methoxyphenyl)meth oxy]-2,4,6,10,12-pentamethyl-13-(triphenylmethoxy)-, (2S,3S,4R,5R,6S,8Z,10S,11R,12S)-

Base Information

Chemical Name:8-Tridecenal, 5,11-bis[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3-[(4-methoxyphenyl)meth oxy]-2,4,6,10,12-pentamethyl-13-(triphenylmethoxy)-, (2S,3S,4R,5R,6S,8Z,10S,11R,12S)-
CAS No.:835929-80-1
Molecular Formula:C57H84O6Si2
Molecular Weight:921.461
Hs Code.:

8-Tridecenal,
5,11-bis[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3-[(4-methoxyphenyl)meth
oxy]-2,4,6,10,12-pentamethyl-13-(triphenylmethoxy)-,
(2S,3S,4R,5R,6S,8Z,10S,11R,12S)-

Synonyms:

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Chemical Property of 8-Tridecenal, 5,11-bis[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3-[(4-methoxyphenyl)meth oxy]-2,4,6,10,12-pentamethyl-13-(triphenylmethoxy)-, (2S,3S,4R,5R,6S,8Z,10S,11R,12S)-

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Technology Process of 8-Tridecenal, 5,11-bis[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3-[(4-methoxyphenyl)meth oxy]-2,4,6,10,12-pentamethyl-13-(triphenylmethoxy)-, (2S,3S,4R,5R,6S,8Z,10S,11R,12S)-

There total 4 articles about 8-Tridecenal, 5,11-bis[[(1,1-dimethylethyl)dimethylsilyl]oxy]-3-[(4-methoxyphenyl)meth oxy]-2,4,6,10,12-pentamethyl-13-(triphenylmethoxy)-, (2S,3S,4R,5R,6S,8Z,10S,11R,12S)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 835929-78-7
(2S,4S,5S)-4-[(Z)-(1R,2R,3S,7S,8R,9S)-2,8-Bis-(tert-butyl-dimethyl-silanyloxy)-1,3,7,9-tetramethyl-10-trityloxy-dec-5-enyl]-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxane

: 835929-80-1
(Z)-(2R,3R,4R,5R,6S,10S,11R,12S)-5,11-Bis-(tert-butyl-dimethyl-silanyloxy)-3-(4-methoxy-benzyloxy)-2,4,6,10,12-pentamethyl-13-trityloxy-tridec-8-enal

Guidance literature:: With sodium hydrogencarbonate; Dess-Martin periodane; In dichloromethane; at 0 ℃; for 2.5h;
DOI:10.1021/ol047686a

Reference yield:

: 835929-79-8
(Z)-(2S,3S,4R,5R,6S,10S,11R,12S)-5,11-Bis-(tert-butyl-dimethyl-silanyloxy)-3-(4-methoxy-benzyloxy)-2,4,6,10,12-pentamethyl-13-trityloxy-tridec-8-en-1-ol

: 835929-80-1
(Z)-(2R,3R,4R,5R,6S,10S,11R,12S)-5,11-Bis-(tert-butyl-dimethyl-silanyloxy)-3-(4-methoxy-benzyloxy)-2,4,6,10,12-pentamethyl-13-trityloxy-tridec-8-enal

Guidance literature:: With sodium hydrogencarbonate; Dess-Martin periodane; In dichloromethane; at 0 ℃; for 2.5h;
DOI:10.1021/ol0476873

Reference yield:

: 835929-77-6
(Z)-(2S,3R,4S,8S,9R,10R)-3,9-Bis-(tert-butyl-dimethyl-silanyloxy)-10-[(2S,4S,5S)-2-(4-methoxy-phenyl)-5-methyl-[1,3]dioxan-4-yl]-2,4,8-trimethyl-undec-5-en-1-ol

: 835929-80-1
(Z)-(2R,3R,4R,5R,6S,10S,11R,12S)-5,11-Bis-(tert-butyl-dimethyl-silanyloxy)-3-(4-methoxy-benzyloxy)-2,4,6,10,12-pentamethyl-13-trityloxy-tridec-8-enal

Guidance literature:: Multi-step reaction with 2 steps

1: 87 percent / DMAP; pyridine / 18 h / Heating

2: Dess-Martin periodinane; NaHCO₃ / CH₂Cl₂ / 2.5 h / 0 °C

With pyridine; dmap; sodium hydrogencarbonate; Dess-Martin periodane; In dichloromethane;
DOI:10.1021/ol047686a