Cyclohexanone, 2-[(1R)-2-nitro-1-(3-nitrophenyl)ethyl]-, (2S)-

Base Information

Chemical Name:Cyclohexanone, 2-[(1R)-2-nitro-1-(3-nitrophenyl)ethyl]-, (2S)-
CAS No.:83976-47-0
Molecular Formula:C14H16N2O5
Molecular Weight:292.291
Hs Code.:
DSSTox Substance ID:DTXSID50474717
Nikkaji Number:J2.096.919I
Wikidata:Q82304828

Synonyms:83976-47-0;Cyclohexanone, 2-[(1R)-2-nitro-1-(3-nitrophenyl)ethyl]-, (2S)-;DTXSID50474717;2alpha-[(R)-1-(3-Nitrophenyl)-2-nitroethyl]cyclohexanone

Suppliers and Price of Cyclohexanone, 2-[(1R)-2-nitro-1-(3-nitrophenyl)ethyl]-, (2S)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of Cyclohexanone, 2-[(1R)-2-nitro-1-(3-nitrophenyl)ethyl]-, (2S)-

Chemical Property:

XLogP3:2.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:3
Exact Mass:292.10592162
Heavy Atom Count:21
Complexity:415

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1CCC(=O)C(C1)C(C[N+](=O)[O-])C2=CC(=CC=C2)[N+](=O)[O-]
Isomeric SMILES:C1CCC(=O)[C@@H](C1)[C@@H](C[N+](=O)[O-])C2=CC(=CC=C2)[N+](=O)[O-]

Technology Process of Cyclohexanone, 2-[(1R)-2-nitro-1-(3-nitrophenyl)ethyl]-, (2S)-

There total 14 articles about Cyclohexanone, 2-[(1R)-2-nitro-1-(3-nitrophenyl)ethyl]-, (2S)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 882-26-8
3-nitro-β-nitrostyrene

: 108-94-1,11119-77-0,9003-41-2,9075-99-4
cyclohexanone

: 83976-47-0
(S)-2-((R)-2-nitro-1-(3-nitrophenyl)ethyl)cyclohexanone

Guidance literature:: cyclohexanone; With N-(((S)-pyrrolidin-2-yl)methyl)phthalimide; In toluene; at 20 ℃; for 0.5h;

With 2,4 dichlorobenzoic acid; In toluene; at 20 ℃; for 0.25h;

3-nitro-β-nitrostyrene; In toluene; at 0 ℃; for 48h; optical yield given as %ee; enantioselective reaction;
DOI:10.1002/ejoc.201101093

Reference yield: 95.0%

: 882-26-8
3-nitro-β-nitrostyrene

: 108-94-1,11119-77-0,9003-41-2,9075-99-4
cyclohexanone

: cis-(2R,1'S)-2-[2'-nitro-1'-(m-nitro-phenyl)-ethyl]-cyclohexanone

: 83976-47-0
(S)-2-((R)-2-nitro-1-(3-nitrophenyl)ethyl)cyclohexanone

Guidance literature:: With (3aR,5S,6R,6aR)-6-hydroxy-2,2-dimethyl-N-((S)-pyrrolidin-2-ylmethyl)tetrahydrofuro[2,3-d][1,3]dioxole-5-carboxamide; at 20 ℃; for 24h; stereoselective reaction;
DOI:10.1016/j.tetasy.2014.02.003