2-Cyclohexen-1-one, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-5-[[[(1,1-dimethylethyl)dimethylsil yl]oxy]methyl]-, (4R,5R)-

Base Information

Chemical Name:2-Cyclohexen-1-one, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-5-[[[(1,1-dimethylethyl)dimethylsil yl]oxy]methyl]-, (4R,5R)-
CAS No.:843613-26-3
Molecular Formula:C₁₉H₃₈O₃Si₂
Molecular Weight:370.68
Hs Code.:

Synonyms:

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Chemical Property of 2-Cyclohexen-1-one, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-5-[[[(1,1-dimethylethyl)dimethylsil yl]oxy]methyl]-, (4R,5R)-

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Technology Process of 2-Cyclohexen-1-one, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-5-[[[(1,1-dimethylethyl)dimethylsil yl]oxy]methyl]-, (4R,5R)-

There total 6 articles about 2-Cyclohexen-1-one, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-5-[[[(1,1-dimethylethyl)dimethylsil yl]oxy]methyl]-, (4R,5R)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 843613-31-0
2-(tert-butyl-dimethyl-silanyloxy)-3-(tert-butyl-dimethyl-silanyloxymethyl)-5-oxo-hexanal

: 843613-26-3
4-(tert-butyl-dimethyl-silanyloxy)-5-(tert-butyl-dimethyl-silanyloxymethyl)-cyclohex-2-enone

Guidance literature:: 2-(tert-butyl-dimethyl-silanyloxy)-3-(tert-butyl-dimethyl-silanyloxymethyl)-5-oxo-hexanal; With sodium hydroxide; In diethyl ether; water; at 20 ℃;

With methanesulfonyl chloride; triethylamine; In dichloromethane; at 0 - 20 ℃;
DOI:10.1016/j.tetlet.2004.12.001

Reference yield:

: 104266-88-8
(4S)-4-benzyl-3-pent-4-enoyl-1,3-oxazolidin-2-one

: 843613-26-3
4-(tert-butyl-dimethyl-silanyloxy)-5-(tert-butyl-dimethyl-silanyloxymethyl)-cyclohex-2-enone

Guidance literature:: Multi-step reaction with 6 steps

1.1: 87 percent / (n-Bu₂)BOTf; (i-Pr)2NEt / CH₂Cl₂ / -78 °C

2.1: lithium borohydride / tetrahydrofuran; methanol / 0 - 20 °C

3.1: imidazole / dimethylformamide / 0 - 20 °C

4.1: Cu(OAc)2*H₂O; O₂ / PdCl₂ / 20 °C

5.1: ozone / methanol; CH₂Cl₂ / -78 °C

5.2: 86 percent / Me₂S / methanol; CH₂Cl₂

6.1: aq. NaOH / diethyl ether; H₂O / 20 °C

6.2: MsCl; Et₃N / CH₂Cl₂ / 0 - 20 °C

With 1H-imidazole; sodium hydroxide; lithium borohydride; copper diacetate; di-n-butylboryl trifluoromethanesulfonate; oxygen; ozone; N-ethyl-N,N-diisopropylamine; palladium dichloride; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; water; N,N-dimethyl-formamide; 1.1: Evans asymmetric aldol reaction / 4.1: Wacker oxidation;
DOI:10.1016/j.tetlet.2004.12.001

Reference yield:

: 843613-24-1
(2R,3R)-2-Allyl-5-methyl-hex-4-ene-1,3-diol

: 843613-26-3
4-(tert-butyl-dimethyl-silanyloxy)-5-(tert-butyl-dimethyl-silanyloxymethyl)-cyclohex-2-enone

Guidance literature:: Multi-step reaction with 4 steps

1.1: imidazole / dimethylformamide / 0 - 20 °C

2.1: Cu(OAc)2*H₂O; O₂ / PdCl₂ / 20 °C

3.1: ozone / methanol; CH₂Cl₂ / -78 °C

3.2: 86 percent / Me₂S / methanol; CH₂Cl₂

4.1: aq. NaOH / diethyl ether; H₂O / 20 °C

4.2: MsCl; Et₃N / CH₂Cl₂ / 0 - 20 °C

With 1H-imidazole; sodium hydroxide; copper diacetate; oxygen; ozone; palladium dichloride; In methanol; diethyl ether; dichloromethane; water; N,N-dimethyl-formamide; 2.1: Wacker oxidation;
DOI:10.1016/j.tetlet.2004.12.001