2-(Cyclopent-2-enyl)aniline

Base Information

• Chemical Name: 2-(Cyclopent-2-enyl)aniline
• CAS No.: 84487-46-7
• Molecular Formula: C11H13N
• Molecular Weight: 159.231
• DSSTox Substance ID: DTXSID30514802
• Nikkaji Number: J1.074.951D
• Mol file: 84487-46-7.mol

Synonyms:2-(cyclopent-2-enyl)aniline;84487-46-7;SCHEMBL10399467;DTXSID30514802;LDYLIAITQPPDNM-UHFFFAOYSA-N;2-(Cyclopent-2-en-1-yl)aniline

Chemical Property of 2-(Cyclopent-2-enyl)aniline

Chemical Property:

• XLogP3: 2.7
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 159.104799419
• Heavy Atom Count: 12
• Complexity: 174

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CC(C=C1)C2=CC=CC=C2N

Technology Process of 2-(Cyclopent-2-enyl)aniline

There total 14 articles about 2-(Cyclopent-2-enyl)aniline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

2-cyclopenten-1-yl chloride (96-40-2) + aniline (62-53-3) → ortho-(cyclopent-2-en-1-yl)aniline (84487-46-7)

Guidance literature:

at 120 ℃; for 2h;

DOI:10.1007/BF00952402

Reference yield: 60.3%

cyclopenta-1,3-diene (542-92-7,25568-84-7,7313-32-8) + aniline (62-53-3) → ortho-(cyclopent-2-en-1-yl)aniline (84487-46-7) + 4-(2-cyclopenten-1-yl)aniline (118560-25-1) + N-dicyclopentenylaniline + N-dicyclopentenyl-2-(2-cyclopentenyl)aniline

Guidance literature:

With aniline hydrochloride; at 230 ℃; for 1.5h; under 7600 - 11400 Torr; Further byproducts given;

Reference yield: 52.0%

2-iodophenylamine (615-43-0) + cyclopentene (142-29-0) → ortho-(cyclopent-2-en-1-yl)aniline (84487-46-7)

Guidance literature:

With tetrabutyl-ammonium chloride; triethylamine; triphenylphosphine; palladium diacetate; In N,N-dimethyl-formamide; at 80 ℃; for 168h;

DOI:10.1016/S0040-4039(00)99075-0

upstream raw materials:

cyclopenta-1,3-diene

aniline

2-cyclopenten-1-yl chloride

N-(2-cyclopentene-1-yl)-aniline

Downstream raw materials:

2,6-di(2-cyclopentenyl)aniline

N-(2-(cyclopent-2-en-1-yl)phenyl)acetamide

2,6-dicyclopentylaniline

N-methanesulfonyl-2-(cyclopent-2-en-1-yl)aniline