5H-Benzo[b]carbazole-1-carboxylic acid, 5-[(3,5-dimethoxyphenyl)methyl]-6,11-dihydro-2-hydroxy-6,11-dioxo-, methyl ester

Base Information

• Chemical Name: 5H-Benzo[b]carbazole-1-carboxylic acid, 5-[(3,5-dimethoxyphenyl)methyl]-6,11-dihydro-2-hydroxy-6,11-dioxo-, methyl ester
• CAS No.: 847027-24-1
• Molecular Formula: C27H21NO7
• Molecular Weight: 471.466
• Mol file: 847027-24-1.mol

Synonyms:

Chemical Property of 5H-Benzo[b]carbazole-1-carboxylic acid, 5-[(3,5-dimethoxyphenyl)methyl]-6,11-dihydro-2-hydroxy-6,11-dioxo-, methyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5H-Benzo[b]carbazole-1-carboxylic acid, 5-[(3,5-dimethoxyphenyl)methyl]-6,11-dihydro-2-hydroxy-6,11-dioxo-, methyl ester

There total 1 articles about 5H-Benzo[b]carbazole-1-carboxylic acid, 5-[(3,5-dimethoxyphenyl)methyl]-6,11-dihydro-2-hydroxy-6,11-dioxo-, methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

5-(3,5-dimethoxy-benzyl)-2,6-dihydroxy-5H-benzo[b]carbazole-1-carboxylic acid methyl ester (847027-10-5) → 5-(3,5-dimethoxy-benzyl)-2-hydroxy-6,11-dioxo-6,11-dihydro-5H-benzo[b]carbazole-1-carboxylic acid methyl ester (847027-24-1)

Guidance literature:

With sodium hydroxide; air; In acetone; at 20 ℃; for 24h;

DOI:10.1016/j.bmc.2004.10.038

Reference yield: 67.0%

5-(3,5-dimethoxy-benzyl)-2-hydroxy-6,11-dioxo-6,11-dihydro-5H-benzo[b]carbazole-1-carboxylic acid methyl ester (847027-24-1) → methyl 2-hydroxy-5-(3,5-dimethoxybenzyl)-5H-benzo[b]carbazole-1-carboxylate

Guidance literature:

With acetic acid; zinc; for 12h; Heating;

DOI:10.1016/j.bmc.2004.10.038

Reference yield: 55.0%

5-(3,5-dimethoxy-benzyl)-2-hydroxy-6,11-dioxo-6,11-dihydro-5H-benzo[b]carbazole-1-carboxylic acid methyl ester (847027-24-1) + acetic anhydride (108-24-7) → methyl 2-acetoxy-5-(3,5-dimethoxybenzyl)-6,11-dioxo-5H-benzo[b]carbazole-1-carboxylate

Guidance literature:

With pyridine; for 2h; Heating;

DOI:10.1016/j.bmc.2004.10.038

upstream raw materials:

5-(3,5-dimethoxy-benzyl)-2,6-dihydroxy-5H-benzo[b]carbazole-1-carboxylic acid methyl ester