N,N'-[Ethene-1,2-diyldi(4,1-phenylene)]bis[4-methoxy-N-(4-methoxyphenyl)aniline]

Base Information

• Chemical Name: N,N'-[Ethene-1,2-diyldi(4,1-phenylene)]bis[4-methoxy-N-(4-methoxyphenyl)aniline]
• CAS No.: 848153-57-1
• Molecular Formula: C42H38N2O4
• Molecular Weight: 634.775
• DSSTox Substance ID: DTXSID30707257
• Mol file: 848153-57-1.mol

Synonyms:848153-57-1;DTXSID30707257;N,N'-[Ethene-1,2-diyldi(4,1-phenylene)]bis[4-methoxy-N-(4-methoxyphenyl)aniline]

Chemical Property of N,N'-[Ethene-1,2-diyldi(4,1-phenylene)]bis[4-methoxy-N-(4-methoxyphenyl)aniline]

Chemical Property:

• XLogP3: 10.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 12
• Exact Mass: 634.28315770
• Heavy Atom Count: 48
• Complexity: 792

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1=CC=C(C=C1)N(C2=CC=C(C=C2)C=CC3=CC=C(C=C3)N(C4=CC=C(C=C4)OC)C5=CC=C(C=C5)OC)C6=CC=C(C=C6)OC

Technology Process of N,N'-[Ethene-1,2-diyldi(4,1-phenylene)]bis[4-methoxy-N-(4-methoxyphenyl)aniline]

There total 9 articles about N,N'-[Ethene-1,2-diyldi(4,1-phenylene)]bis[4-methoxy-N-(4-methoxyphenyl)aniline] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

4-[bis(4-methoxyphenyl)amino]benzaldehyde (89115-20-8) → (E)-4,4'-(ethene-1,2-diyl)bis(N,N-bis(4-methoxyphenyl)aniline) (848153-57-1)

Guidance literature:

4-[bis(4-methoxyphenyl)amino]benzaldehyde; With pyridine; titanium tetrachloride; zinc; In tetrahydrofuran; at 0 ℃; Inert atmosphere; Reflux;

With water; In tetrahydrofuran; for 0.333333h; Inert atmosphere;

DOI:10.1002/chem.201502741

Reference yield: 80.0%

bis(4-methoxyphenyl)amine (101-70-2) + (E)-2-(3-bromophenyl)-1-(4-bromophenyl)ethene (106948-30-5) → (E)-4,4'-(ethene-1,2-diyl)bis(N,N-bis(4-methoxyphenyl)aniline) (848153-57-1)

Guidance literature:

With tris-(o-tolyl)phosphine; sodium t-butanolate; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; In toluene;

DOI:10.1246/bcsj.73.1021

Reference yield: 78.0%

(E)-4,4'-dibromostilbene (18869-30-2) + bis(4-methoxyphenyl)amine (101-70-2) → (E)-4,4'-(ethene-1,2-diyl)bis(N,N-bis(4-methoxyphenyl)aniline) (848153-57-1)

Guidance literature:

With 1,1'-bis-(diphenylphosphino)ferrocene; sodium t-butanolate; dipalladiumtris(benzylideneacetone); In toluene; at 110 ℃; for 15h;

DOI:10.1039/b415018j

upstream raw materials:

bis(4-methoxyphenyl)amine

(E)-2-(3-bromophenyl)-1-(4-bromophenyl)ethene

(E)-4,4'-dibromostilbene

diethyl (4-bromobenzyl)phosphonate