Gibberellin A8-catabolite

Base Information

Chemical Name:Gibberellin A8-catabolite
CAS No.:78791-79-4
Molecular Formula:C₁₉H₂₂O₇
Molecular Weight:362.379
Hs Code.:
DSSTox Substance ID:DTXSID80332093
Nikkaji Number:J2.777.649C
Wikidata:Q27110171
Metabolomics Workbench ID:28583

Synonyms:Gibberellin A8-catabolite;78791-79-4;GA8-catabolite;(1S,2S,3S,4S,5R,9R,12S)-5,12-dihydroxy-4-methyl-13-methylidene-6-oxotetracyclo[10.2.1.01,9.03,8]pentadec-7-ene-2,4-dicarboxylic acid;CHEBI:29604;DTXSID80332093;LMPR0104170027;Q27110171;(1alpha,2beta,4bbeta,10beta)-2,7-dihydroxy-1-methyl-8-methylene-3-oxogibb-4-ene-1,10-dicarboxylic acid

Suppliers and Price of Gibberellin A8-catabolite

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Gibberellin A8-catabolite

Chemical Property:

Vapor Pressure:3.22E-19mmHg at 25°C
Boiling Point:642.5°Cat760mmHg
Flash Point:356.4°C
PSA：132.13000
Density:1.52g/cm³
LogP:0.75540
XLogP3:-0.4
Hydrogen Bond Donor Count:4
Hydrogen Bond Acceptor Count:7
Rotatable Bond Count:2
Exact Mass:362.13655304
Heavy Atom Count:26
Complexity:798

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1(C2C(C34CC(=C)C(C3)(CCC4C2=CC(=O)C1O)O)C(=O)O)C(=O)O
Isomeric SMILES:C[C@@]1([C@H]2[C@@H]([C@@]34CC(=C)[C@@](C3)(CC[C@H]4C2=CC(=O)[C@@H]1O)O)C(=O)O)C(=O)O

Technology Process of Gibberellin A8-catabolite

There total 4 articles about Gibberellin A8-catabolite which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 6800-32-4
C₁₉H₂₄O₇

: 78791-79-4
ent-3α,13-dihydroxy-2-oxo-20-norgibberella-1(10),16-diene-7,19-dioic acid

Guidance literature:: Multi-step reaction with 3 steps

1: 1.34 g / 18-crown-6-ether / acetonitrile / 0.5 h / Heating

2: 238 mg / pyridinium chlorochromate, sodium acetate / CH₂Cl₂ / 0.67 h

3: 14 mg / activated zinc dust, glacial acetic acid / 2 h

With 18-crown-6 ether; sodium acetate; acetic acid; pyridinium chlorochromate; zinc; In dichloromethane; acetonitrile;
DOI:10.1039/P19810001083

Reference yield:

: 78699-14-6
diphenacyl ent-2β,3α,13-trihydroxy-20-norgibberella-1(10),16-diene-7,19-dioate

: 78791-79-4
ent-3α,13-dihydroxy-2-oxo-20-norgibberella-1(10),16-diene-7,19-dioic acid

Guidance literature:: Multi-step reaction with 2 steps

1: 238 mg / pyridinium chlorochromate, sodium acetate / CH₂Cl₂ / 0.67 h

2: 14 mg / activated zinc dust, glacial acetic acid / 2 h

With sodium acetate; acetic acid; pyridinium chlorochromate; zinc; In dichloromethane;
DOI:10.1039/P19810001083

Reference yield:

: 77-06-5,25274-45-7,76675-41-7,83313-40-0
gibberellic acid

: 78791-79-4
ent-3α,13-dihydroxy-2-oxo-20-norgibberella-1(10),16-diene-7,19-dioic acid

Guidance literature:: Multi-step reaction with 4 steps

1: 0.8M aq. potassium hydroxide / 20 h

2: 1.34 g / 18-crown-6-ether / acetonitrile / 0.5 h / Heating

3: 238 mg / pyridinium chlorochromate, sodium acetate / CH₂Cl₂ / 0.67 h

4: 14 mg / activated zinc dust, glacial acetic acid / 2 h

With potassium hydroxide; 18-crown-6 ether; sodium acetate; acetic acid; pyridinium chlorochromate; zinc; In dichloromethane; acetonitrile;
DOI:10.1039/P19810001083