Bis(4-chlorophenyl)phosphine

Base Information

Chemical Name:Bis(4-chlorophenyl)phosphine
CAS No.:86190-45-6
Molecular Formula:C12H9Cl2P
Molecular Weight:255.083
Hs Code.:
DSSTox Substance ID:DTXSID00479237
Nikkaji Number:J2.231.794F
Wikidata:Q82313218

Synonyms:86190-45-6;BIS(4-CHLOROPHENYL)PHOSPHINE;Phosphine, bis(4-chlorophenyl)-;SCHEMBL1486392;DTXSID00479237

Suppliers and Price of Bis(4-chlorophenyl)phosphine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of Bis(4-chlorophenyl)phosphine

Chemical Property:

XLogP3:4.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:2
Exact Mass:253.9818927
Heavy Atom Count:15
Complexity:162

Purity/Quality:: 98%min ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC(=CC=C1PC2=CC=C(C=C2)Cl)Cl

Technology Process of Bis(4-chlorophenyl)phosphine

There total 3 articles about Bis(4-chlorophenyl)phosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 15948-60-4
bis(4-chlorophenyl)phosphine oxide

: 86190-45-6
bis(4-chlorophenyl)phosphane

Guidance literature:: With diisobutylaluminium hydride; In tetrahydrofuran; at 25 ℃; for 0.166667h;
DOI:10.1021/ol0517832

Reference yield: 83.0%

: 86190-45-6
bis(4-chlorophenyl)phosphane

Guidance literature:

Reference yield:

: 106-46-7,84348-21-0
para-dichlorobenzene

: 86190-45-6
bis(4-chlorophenyl)phosphane

Guidance literature:: Multi-step reaction with 2 steps

1.1: magnesium / tetrahydrofuran / 4 h / 20 °C / Inert atmosphere; Schlenk technique

1.2: 2.25 h / 20 °C / Inert atmosphere; Schlenk technique; Cooling with ice

2.1: diisobutylaluminium hydride / tetrahydrofuran; hexane / 0.75 h / 20 °C / Inert atmosphere; Schlenk technique

With diisobutylaluminium hydride; magnesium; In tetrahydrofuran; hexane;
DOI:10.1021/ja509381w