Benzene, [(1E)-7-chloro-1-heptenyl]-

Base Information

• Chemical Name: Benzene, [(1E)-7-chloro-1-heptenyl]-
• CAS No.: 86542-33-8
• Molecular Formula: C13H17Cl
• Molecular Weight: 208.731
• Mol file: 86542-33-8.mol

Synonyms:(E)-1-chloro-7-phenyl-6-heptene;(E)-(7-chlorohept-1-en-1-yl)benzene;(E)-7-chloro-1-phenyl-1-heptene;Benzene,[(1E)-7-chloro-1-heptenyl];

Chemical Property of Benzene, [(1E)-7-chloro-1-heptenyl]-

Chemical Property:

• PSA: 0.00000
• LogP: 4.49900

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzene, [(1E)-7-chloro-1-heptenyl]-

There total 8 articles about Benzene, [(1E)-7-chloro-1-heptenyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

4-chlorobutyl bromide (6940-78-9) + Cinnamyl acetate (21040-45-9) → (E)-(7-chlorohept-1-en-1-yl)benzene (86542-33-8)

Guidance literature:

Cinnamyl acetate; With manganese; trifluoroacetic acid; cobalt(II) bromide; In acetonitrile; at 20 ℃; for 0.0833333h;

4-chlorobutyl bromide; With pyridine; In acetonitrile; at 80 ℃;

DOI:10.1002/anie.201104390

Reference yield: 58.0%

(E)-1-styryltetrahydro-1H-thiophen-1-ium trifluoromethanesulfonate + 1,3-dioxoisoindolin-2-yl 6-chlorohexanoate → (E)-(7-chlorohept-1-en-1-yl)benzene (86542-33-8)

Guidance literature:

With eosin; tert-butylammonium hexafluorophosphate(V); N-ethyl-N,N-diisopropylamine; In diethyl ether; tert-butyl methyl ether; at 30 ℃; for 9h; Schlenk technique; Inert atmosphere; Irradiation;

DOI:10.1021/acs.orglett.0c03074

Reference yield: 48.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + 1-bromo-5-chloropentane (54512-75-3) → (E)-(7-chlorohept-1-en-1-yl)benzene (86542-33-8)

Guidance literature:

With bis(cyclopentadienyl)titanium dichloride; butyl magnesium bromide; In diethyl ether; at 0 ℃; for 6h;

DOI:10.1246/bcsj.76.2209

upstream raw materials:

6-chlorohexanal

benzyltriphenylphosphonium bromide

styrene

1-bromo-5-chloropentane

Downstream raw materials:

(E)-1-nitro-7-phenyl-6-heptene

(Z)-1-nitro-7-phenyl-6-heptene