3-Azido-4-(cyclohex-1-en-1-yl)thiophene

Base Information

Chemical Name:3-Azido-4-(cyclohex-1-en-1-yl)thiophene
CAS No.:86660-74-4
Molecular Formula:C₁₀H₁₁N₃S
Molecular Weight:205.283
Hs Code.:
DSSTox Substance ID:DTXSID20517589
Wikidata:Q82379699

Synonyms:86660-74-4;3-Azido-4-(cyclohex-1-en-1-yl)thiophene;DTXSID20517589

Suppliers and Price of 3-Azido-4-(cyclohex-1-en-1-yl)thiophene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 3-Azido-4-(cyclohex-1-en-1-yl)thiophene

Chemical Property:

XLogP3:4.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:2
Exact Mass:205.06736854
Heavy Atom Count:14
Complexity:281

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1CCC(=CC1)C2=CSC=C2N=[N+]=[N-]

Technology Process of 3-Azido-4-(cyclohex-1-en-1-yl)thiophene

There total 2 articles about 3-Azido-4-(cyclohex-1-en-1-yl)thiophene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 108-94-1,11119-77-0,9003-41-2,9075-99-4
cyclohexanone

: 86660-74-4
3-(cyclohex-1-enyl)-4-azidothiophen

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) n-BuLi, 3.) p-TsOH

2: 1.) n-BuLi, 2.) toluene-p-sulphonyl azide, 3.) tetrasodium pyrophosphate

With sodium pyrophosphate; n-butyllithium; 4-toluenesulfonyl azide; toluene-4-sulfonic acid;

Reference yield:

: 38071-56-6
3-bromo-2-cyclohex-1-enyl-thiophene

: 86660-74-4
3-(cyclohex-1-enyl)-4-azidothiophen

: 3-azido-2-cyclohex-1-enylthiophen

Guidance literature:: With sodium pyrophosphate; n-butyllithium; 4-toluenesulfonyl azide; Yield given. Multistep reaction. Yields of byproduct given;

Reference yield: 95.0%

: 873-51-8
phenylborondichloride

: 86660-74-4
3-(cyclohex-1-enyl)-4-azidothiophen

: 86660-76-6
((C₄H₂S)(C₆H₈)N(C₆H₅)B)2O

Guidance literature:: With water; In benzene; treatment of borane with S-compd. (in benzene, 1 h, room temp.), then hydrolysis;
DOI:10.1039/c39830000396