6-Azido-6-deoxy-alpha-D-mannopyranose

Base Information

Chemical Name:6-Azido-6-deoxy-alpha-D-mannopyranose
CAS No.:120202-54-2
Molecular Formula:C₆H₁₁N₃O₅
Molecular Weight:205.17
Hs Code.:
UNII:E7H2ZNS33O
DSSTox Substance ID:DTXSID60923266
Wikidata:Q27276971

Synonyms:6-Azido-6-deoxy-alpha-D-mannopyranose;E7H2ZNS33O;120202-54-2;CCRIS 4990;UNII-E7H2ZNS33O;alpha-D-Mannopyranose, 6-azido-6-deoxy-;6-Azido-6-deoxyhexopyranose;DTXSID60923266;6-AZIDO-6-DEOXY-.ALPHA.-D-MANNOPYRANOSE;.ALPHA.-D-MANNOPYRANOSE, 6-AZIDO-6-DEOXY-;Q27276971

Suppliers and Price of 6-Azido-6-deoxy-alpha-D-mannopyranose

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
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Chemical Property of 6-Azido-6-deoxy-alpha-D-mannopyranose

Chemical Property:

Boiling Point:°Cat760mmHg
Flash Point:°C
Density:g/cm³
XLogP3:-1.6
Hydrogen Bond Donor Count:4
Hydrogen Bond Acceptor Count:7
Rotatable Bond Count:2
Exact Mass:205.06987046
Heavy Atom Count:14
Complexity:244

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C(C1C(C(C(C(O1)O)O)O)O)N=[N+]=[N-]
Isomeric SMILES:C([C@@H]1[C@H]([C@@H]([C@@H]([C@H](O1)O)O)O)O)N=[N+]=[N-]

Technology Process of 6-Azido-6-deoxy-alpha-D-mannopyranose

There total 3 articles about 6-Azido-6-deoxy-alpha-D-mannopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 1,2,3-tri-O-acetyl-6-azido-4-O-benzoyl-6-deoxy-α-D-mannopyranose

: 120202-54-2,138332-00-0,138332-01-1
6-azido-6-deoxy-D-mannopyranose

Guidance literature:: With methanol; sodium methylate; for 0.5h;

Reference yield:

: 40789-24-0
methyl 2,3-O-isopropylidene-6-O-p-toluenesulfonyl-α-D-mannofuranoside

: 120202-54-2,138332-00-0,138332-01-1
6-azido-6-deoxy-D-mannopyranose

Guidance literature:: Multi-step reaction with 2 steps

1: 98 percent / LiN₃ / dimethylformamide / 19 h / 50 - 60 °C

2: trifluoroacetic acid; H₂O / 5.5 h / 40 - 50 °C

With lithium azide; In water; N,N-dimethyl-formamide; trifluoroacetic acid;
DOI:10.1016/S0008-6215(97)10014-3

Reference yield:

: (R)-2-Azido-1-((3aS,4R,6S,6aS)-6-methoxy-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxol-4-yl)-ethanol

: 120202-54-2,138332-00-0,138332-01-1
6-azido-6-deoxy-D-mannopyranose

: 138332-00-0,138332-01-1
6-azido-6-deoxy-β-D-mannopyranose

Guidance literature:: In water; trifluoroacetic acid; at 40 - 50 ℃; for 5.5h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
DOI:10.1016/S0008-6215(97)10014-3