1,3,5-Tris(2-methylphenyl)benzene

Base Information

Chemical Name:1,3,5-Tris(2-methylphenyl)benzene
CAS No.:87226-88-8
Molecular Formula:C27H24
Molecular Weight:348.47900
Hs Code.:
European Community (EC) Number:804-393-7
DSSTox Substance ID:DTXSID20434707
Nikkaji Number:J808.151D
Wikidata:Q82249191
Mol file:87226-88-8.mol

Synonyms:1,3,5-tris(2-methylphenyl)benzene;87226-88-8;1,1':3',1''-Terphenyl, 2,2''-dimethyl-5'-(2-methylphenyl)-;1,3,5-Tri-o-tolylbenzene;DTXSID20434707;1,3,5-Tris(2-methylphenyl)benzene, 97%

Suppliers and Price of 1,3,5-Tris(2-methylphenyl)benzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
1,3,5-Tris(2-methylphenyl)benzene 97%
1g
$ 91.80

AK Scientific
1,3,5-Tris(2-methylphenyl)benzene
1g
$ 171.00

Total 7 raw suppliers

Chemical Property of 1,3,5-Tris(2-methylphenyl)benzene

Chemical Property:

Melting Point:132-136°C
Boiling Point:466.0±40.0 °C(Predicted)
PSA：0.00000
Density:1.043±0.06 g/cm3(Predicted)
LogP:7.61280
XLogP3:7.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:3
Exact Mass:348.187800766
Heavy Atom Count:27
Complexity:374

Purity/Quality:

99.0% ^*data from raw suppliers

1,3,5-Tris(2-methylphenyl)benzene 97% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:Xn
Statements: 22-36
Safety Statements: 26

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC=CC=C1C2=CC(=CC(=C2)C3=CC=CC=C3C)C4=CC=CC=C4C

Technology Process of 1,3,5-Tris(2-methylphenyl)benzene

There total 1 articles about 1,3,5-Tris(2-methylphenyl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 766-47-2
1-ethynyl-2-methylbenzene

: 136612-95-8
2,2″-dimethyl-4′-(o-tolyl)-1,1′:2′,1″-terphenyl

: 87226-88-8
2,2-dimethyl-5'-(o-tolyl)-1,1':3',1-terphenyl

: 259090-89-6
(Z)-2,2‘-(but-1-en-3-yne-1,4-diyl)bis(methylbenzene)

: 2,4-bis(2-methylphenyl)but-1-en-3-yne

Guidance literature:: With (p-cymene)ruthenium(II) chloride; ethene; tricyclohexylphosphine; In toluene; at 80 ℃; for 24h; under 760.051 Torr;
DOI:10.1016/j.catcom.2013.06.023

Reference yield:

: 87226-88-8
2,2-dimethyl-5'-(o-tolyl)-1,1':3',1-terphenyl

: C₄₉H₆₉N₂P₃Pd⁽²⁺⁾*2BF₄^(1-)

Guidance literature:: Multi-step reaction with 2 steps

1.1: n-butyllithium; potassium tert-butylate / tetrahydrofuran; hexane / 2.67 h / -78 - 20 °C / Inert atmosphere; Schlenk technique

1.2: -78 - 20 °C / Inert atmosphere; Schlenk technique

2.1: [D₃]acetonitrile / 2 h / 20 °C

With n-butyllithium; potassium tert-butylate; In tetrahydrofuran; hexane; [D₃]acetonitrile;
DOI:10.1021/om400424a