2,5,8,11-Tetraoxatridec-12-ene

Base Information

• Chemical Name: 2,5,8,11-Tetraoxatridec-12-ene
• CAS No.: 26256-87-1
• Molecular Formula: C9H18 O4
• Molecular Weight: 190.24
• European Community (EC) Number: 247-553-6
• DSSTox Substance ID: DTXSID00949122
• Nikkaji Number: J308.414K
• Wikidata: Q82926964
• Mol file: 26256-87-1.mol

Synonyms:26256-87-1;2,5,8,11-Tetraoxatridec-12-ene;3,6,9,12-Tetraoxatridec-2-ene;EINECS 247-553-6;1-[2-(2-ethenoxyethoxy)ethoxy]-2-methoxyethane;SCHEMBL19475;TRI(ETHYLENE GLYCOL) METHYL VINYL ETHER, 98;DTXSID00949122;2,5,8,11-Tetraoxa-12-tridecene;Triethylene Glycol Methyl Vinyl Ether;AKOS006228281;2-[2-(2-methoxyethoxy)ethoxy]ethyl vinyl ether

Chemical Property of 2,5,8,11-Tetraoxatridec-12-ene

Chemical Property:

• Refractive Index: n20/D 1.439(lit.)
• Boiling Point: 242 °C(lit.)
• Flash Point: 88 °C
• PSA: 36.92000
• Density: 0.99 g/mL at 25 °C(lit.)
• LogP: 0.82610
• XLogP3: 0.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 10
• Exact Mass: 190.12050905
• Heavy Atom Count: 13
• Complexity: 106

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COCCOCCOCCOC=C

Technology Process of 2,5,8,11-Tetraoxatridec-12-ene

There total 3 articles about 2,5,8,11-Tetraoxatridec-12-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

vinyl acetate (108-05-4,9003-20-7) + triethylene glucol monomethyl ether (112-35-6,95507-80-5) → triethylene glycol monomethyl monovinylether (26256-87-1)

Guidance literature:

With bis(1,5-cyclooctadiene)diiridium(I) dichloride; sodium carbonate; In toluene; at 100 ℃; for 3h; Inert atmosphere;

DOI:10.1016/j.tet.2012.02.025

Reference yield: 84.0%

triethylene glucol monomethyl ether (112-35-6,95507-80-5) + ethyl vinyl ether (109-92-2,25104-37-4) → triethylene glycol monomethyl monovinylether (26256-87-1)

Guidance literature:

With 1,10-Phenanthroline; palladium diacetate; In dichloromethane; at 60 ℃; Schlenk technique; Inert atmosphere; Autoclave;

DOI:10.1002/pola.26463

Reference yield: 60.0%

triethylene glucol monomethyl ether (112-35-6,95507-80-5) + acetylene (74-86-2,25067-58-7) → triethylene glycol monomethyl monovinylether (26256-87-1)

Guidance literature:

With potassium hydroxide; dimethyl sulfoxide; at 76 - 84 ℃; for 7.5h;

upstream raw materials:

triethylene glucol monomethyl ether

acetylene

vinyl acetate

ethyl vinyl ether

Downstream raw materials:

benzyl vinyl ether

triethylene glycol benzyl methyl ether