Iron, hexacarbonyl[m-(disulfur-kS,kS':kS,kS')]di-, (Fe-Fe)

Base Information

• Chemical Name: Iron, hexacarbonyl[m-(disulfur-kS,kS':kS,kS')]di-, (Fe-Fe)
• CAS No.: 14243-23-3
• Molecular Formula: C6Fe2 O6 S2
• Molecular Weight: 343.888
• Mol file: 14243-23-3.mol

Synonyms:Iron,hexacarbonyl[m-(disulfur-S,S':S,S')]di-,(Fe-Fe); Sulfur, mol. (S2), iron complex; Hexacarbonyldisulfidodiiron;Hexacarbonyldithioxodiiron

Chemical Property of Iron, hexacarbonyl[m-(disulfur-kS,kS':kS,kS')]di-, (Fe-Fe)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Iron, hexacarbonyl[m-(disulfur-kS,kS':kS,kS')]di-, (Fe-Fe)

There total 5 articles about Iron, hexacarbonyl[m-(disulfur-kS,kS':kS,kS')]di-, (Fe-Fe) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.0%

diiron nonacarbonyl (15321-51-4) + 2-(benzylsulfinothioyl)isoindoline-1,3-dione (33704-38-0) → (μ-dithio)bis(tricarbonyliron) (14243-23-3) + Fe2(CO)6[C8H4NO2S][SCH2C6H5] (106256-75-1) + bis-iron(tricarbonyl)-bis(μ2-benzylthiol) + [Fe3(CO)9(μ3-S)2]

Guidance literature:

In tetrahydrofuran; stirring of 3.87E-2 mol Fe2(CO)9, 1.43E-2 mol N-(benzyldithio)phthalimide and THF for 14 h; extraction with ether; concn.;; chromy. (florisil, hexane: gives Fe2(CO)6S2 and Fe3(CO)9S2, ethyl acetate: gives (Fe(CO)3SCH2C6H5)2, futher ethyl acetate: gives Fe2(CO)6(C8H4NO2S)(SCH2C6H5);;

DOI:10.1016/S0020-1693(00)81323-7

Reference yield: 27.0%

Fe2(CO)6(μ-STe)2 (138367-92-7) + phenylacetylene (536-74-3) → (μ-dithio)bis(tricarbonyliron) (14243-23-3) + Fe2(CO)6(μ-SC(Ph)=C(H)Te) + (CO)6Fe2(μ-SC(H)=C(Ph)Te) (162719-03-1)

Guidance literature:

With NaOAc; In methanol; Ar-atmosphere; stirring (room temp., 36 h); filtering, evapn. (vac.), CH2Cl2 addn., filtering, chromy. (SiO2, hexane); elem. anal.;

Reference yield: 23.0%

Fe3(CO)9(μ-S)2 + dimethylphenylphosphine(carbonyl)5tungsten (42565-94-6) → (μ-dithio)bis(tricarbonyliron) (14243-23-3) + Fe3(CO)9(μ3-S)(μ4-){W(CO)5} (118514-44-6) + Fe3(CO)9(μ3-S)(μ4-){W(CO)4(PMe2Ph)} (118514-46-8) + WFe3(CO)11(PMe2Ph)(μ3-S)2 (118514-48-0)

Guidance literature:

In hexane; Irradiation (UV/VIS); further products: WFe2(CO)9(PMe2Ph)(μ3-S)2 1.3%, Fe3(CO)8(PMe2Ph)μ3-S)2 2.5%; under dry N2, photolyzed under continuous purge of N2 for 2 h, color change from red to brown; evapn. (brown residue), soln. (CH2Cl2), chromy. (TLC, CH2Cl2/hexane (2/8)); elem. anal.;

upstream raw materials:

diiron nonacarbonyl

2-(benzylsulfinothioyl)isoindoline-1,3-dione

dimethylphenylphosphine(carbonyl)5tungsten

Fe3(CO)9(μ3-S)(μ4-){W(CO)4(PMe2Ph)}

Downstream raw materials:

WFe2(CO)9(PMe2Ph)(μ3-S)(μ4-S){W(CO)5}

WFe2(CO)9(PMe2Ph)(μ3-S)2

{μ-(Ph3P)2PtS2}Fe2(CO)6

[SC(C₆H₅)C(Si(CH₃)3)S]Fe₂(CO)6

Refernces

• 1、 Adams, Richard D.,Babin, James E.,Wang, Jin-Guu,Wu, Wengan. "Cluster synthesis. 24. Synthesis and characterization of new sulfur-containing tungsten-iron carbonyl cluster complexes". . p. 703 - 709. Retrieved 2008/10/08.