(Z)-11-[(2R)-2-[(E)-pent-3-enyl]oxiran-2-yl]undec-9-enoic Acid

Base Information

• Chemical Name: (Z)-11-[(2R)-2-[(E)-pent-3-enyl]oxiran-2-yl]undec-9-enoic Acid
• CAS No.: 100019-37-2
• Deprecated CAS: 126643-97-8
• Molecular Formula: C₁₈H₃₀O₃
• Molecular Weight: 294.434
• Mol file: 100019-37-2.mol

Synonyms:100019-37-2;(Z)-11-[(2R)-2-[(E)-pent-3-enyl]oxiran-2-yl]undec-9-enoic Acid;9-Undecenoic acid, 11-(3-(2-pentenyl)oxiranyl)-, (2alpha(Z),3alpha(Z))-

Chemical Property of (Z)-11-[(2R)-2-[(E)-pent-3-enyl]oxiran-2-yl]undec-9-enoic Acid

Chemical Property:

• Vapor Pressure: 3.33E-07mmHg at 25°C
• Boiling Point: 391.1°Cat760mmHg
• Flash Point: 128.8°C
• Density: 0.988g/cm³
• XLogP3: 4.7
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 13
• Exact Mass: 294.21949481
• Heavy Atom Count: 21
• Complexity: 346

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC=CCCC1(CO1)CC=CCCCCCCCC(=O)O
• Isomeric SMILES: C/C=C/CC[C@]1(CO1)C/C=C\CCCCCCCC(=O)O

Technology Process of (Z)-11-[(2R)-2-[(E)-pent-3-enyl]oxiran-2-yl]undec-9-enoic Acid

There total 2 articles about (Z)-11-[(2R)-2-[(E)-pent-3-enyl]oxiran-2-yl]undec-9-enoic Acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(9Z,12Z,15Z)-octadeca-9-12,15-trienoic acid (463-40-1,1955-33-5,21661-10-9,21661-09-6,21661-13-2,21661-11-0) → 12,13-Epoxylinolenic acid (349112-29-4,100019-37-2,88159-18-6) + 9(10)-epoxy-10,12(Z),15(Z)-octadecatrienoic acid (868281-09-8,36747-82-7) + 15,16-cis-epoxy-octadeca-9Z,12Z-dienoic acid (64044-08-2)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; for 0.5h;

DOI:10.1007/s11745-017-4271-0

Reference yield:

(9Z,12Z,15Z)-octadeca-9-12,15-trienoic acid (463-40-1,1955-33-5,21661-10-9,21661-09-6,21661-13-2,21661-11-0) → 12,13-Epoxylinolenic acid (349112-29-4,100019-37-2,88159-18-6) + 15-16-monoepoxyoctadeca-9,12-dieneoic acid (710296-22-3,64044-08-2) + 9(10)-epoxy-10,12(Z),15(Z)-octadecatrienoic acid (868281-09-8,36747-82-7)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid;

DOI:10.1246/cl.1984.409

upstream raw materials:

(9Z,12Z,15Z)-octadeca-9-12,15-trienoic acid

Refernces

• 1、 Kato, Tadahiro,Yamaguchi, Yoshihiro,Hirano, Takumi,Yokoyama, Toshiro,Uyehara, Tadao,et al.. "UNSATURATED HYDROXY FATTY ACIDS, THE SELF DEFENSIVE SUBSTANCES IN RICE PLANT AGAINST RICE BLAST DISEASE". . p. 409 - 412. Retrieved 2007/10/02.