1,10,19,28-Tetrastannacyclohexatriacontane, 1,1,10,10,19,19,28,28-octaphenyl-

Base Information

• Chemical Name: 1,10,19,28-Tetrastannacyclohexatriacontane, 1,1,10,10,19,19,28,28-octaphenyl-
• CAS No.: 87518-41-0
• Molecular Formula: C₈₀H₁₀₄Sn₄
• Molecular Weight: 1540.55
• Mol file: 87518-41-0.mol

Synonyms:

Chemical Property of 1,10,19,28-Tetrastannacyclohexatriacontane, 1,1,10,10,19,19,28,28-octaphenyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,10,19,28-Tetrastannacyclohexatriacontane, 1,1,10,10,19,19,28,28-octaphenyl-

There total 1 articles about 1,10,19,28-Tetrastannacyclohexatriacontane, 1,1,10,10,19,19,28,28-octaphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 25.0%

1,8-dibromooctane (4549-32-0) + 1,8-bis(bromodiphenylstannyl)octane (87518-48-7) → 1,1,10,10,19,19,28,28-octaphenyl-1,10,19,28-tetrastannacyclohexatricontane (87518-41-0) + 1,1,10,10-tetraphenyl-1,10-distannacyclooctadecane (87531-98-4)

Guidance literature:

With iodine; magnesium; In tetrahydrofuran; (N2); to suspn. of Mg and I2 at 25°C added over 1 h soln. of Br(CH2)8Br, stirred for 4 h, sepd. from excess of Mg, diluted with THF, added over 2.5 h to Sn-compd. soln. at 0°C, allowed to warm to 25°C, stirred for 10 h; satd. aq. NH4Cl added at 0°C, aq. layer extd. (ether), combined ethereal solns. washed (satd. aq. NaCl), dried (MgSO4), filtered, concd., chromd. (MeCN/THF), recrystd. (hexane or MeCN/THF); elem. anal.;

DOI:10.1021/om00079a003

upstream raw materials:

1,8-dibromooctane

1,8-bis(bromodiphenylstannyl)octane