(Pentane-1,5-diyl)bis[bromo(diphenyl)stannane]

Base Information

Chemical Name:(Pentane-1,5-diyl)bis[bromo(diphenyl)stannane]
CAS No.:87518-46-5
Molecular Formula:C29H30Br2Sn2
Molecular Weight:781.80600
Hs Code.:
DSSTox Substance ID:DTXSID50531218
Wikidata:Q82402912

Synonyms:(Pentane-1,5-diyl)bis[bromo(diphenyl)stannane];87518-46-5;DTXSID50531218

Suppliers and Price of (Pentane-1,5-diyl)bis[bromo(diphenyl)stannane]

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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Total 0 raw suppliers

Chemical Property of (Pentane-1,5-diyl)bis[bromo(diphenyl)stannane]

Chemical Property:

Boiling Point:620.9±65.0 °C(Predicted)
PSA：0.00000
LogP:-0.58770
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:10
Exact Mass:775.87319
Heavy Atom Count:33
Complexity:460

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)[Sn](CCCCC[Sn](C2=CC=CC=C2)(C3=CC=CC=C3)Br)(C4=CC=CC=C4)Br

Technology Process of (Pentane-1,5-diyl)bis[bromo(diphenyl)stannane]

There total 1 articles about (Pentane-1,5-diyl)bis[bromo(diphenyl)stannane] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

: 5588-71-6
1,5-bis(triphenylstannyl)pentane

: 87518-53-4
1-(bromodiphenylstannyl)-5-(triphenylstannyl)pentane

: 87518-46-5
1,5-bis(bromodiphenylstannyl)pentane

Guidance literature:: With hydrogen bromide; In dichloromethane; to soln. of Sn compd. added slowly (2 h) soln. of 2.1 equiv of HBr at -78°C, slowly warmed to 25°C, reacted for 8-10 h; evapd. (vac.), chromd. (MeCN or MeCN/THF);
DOI:10.1021/om00079a003

Reference yield: 18.6%

: 111-24-0
1,5-dibromo-pentane

: 87518-46-5
1,5-bis(bromodiphenylstannyl)pentane

: 87518-39-6
1,1,7,7,13,13,19,19-octaphenyl-1,7,13,19-tetrastannacyclotetracosane

: 87518-35-2
1,1,7,7-tetraphenyl-1,7-distannacyclododecane

Guidance literature:: With iodine; magnesium; In tetrahydrofuran; (N2); to suspn. of Mg and I2 at 25°C added over 1 h soln. of Br(CH2)5Br, stirred for 4 h, sepd. from excess of Mg, diluted with THF, added over 2.5 h to Sn-compd. soln. at 0°C, allowed to warm to 25°C, stirred for 10 h; satd. aq. NH4Cl added at 0°C, aq. layer extd. (ether), combined ethereal solns. washed (satd. aq. NaCl), dried (MgSO4), filtered, concd., chromd. (MeCN/THF), recrystd. (hexane); elem. anal.;
DOI:10.1021/om00079a003