4-(Benzenesulfonyl)-5-(dimethoxymethyl)-2-methylcyclohex-2-en-1-one

Base Information

Chemical Name:4-(Benzenesulfonyl)-5-(dimethoxymethyl)-2-methylcyclohex-2-en-1-one
CAS No.:87640-83-3
Molecular Formula:C₁₆H₂₀O₅S
Molecular Weight:324.398
Hs Code.:
DSSTox Substance ID:DTXSID00510876

Synonyms:87640-83-3;DTXSID00510876;4-(Benzenesulfonyl)-5-(dimethoxymethyl)-2-methylcyclohex-2-en-1-one

Suppliers and Price of 4-(Benzenesulfonyl)-5-(dimethoxymethyl)-2-methylcyclohex-2-en-1-one

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 4-(Benzenesulfonyl)-5-(dimethoxymethyl)-2-methylcyclohex-2-en-1-one

Chemical Property:

XLogP3:1.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:5
Exact Mass:324.10314491
Heavy Atom Count:22
Complexity:521

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC(C(CC1=O)C(OC)OC)S(=O)(=O)C2=CC=CC=C2

Technology Process of 4-(Benzenesulfonyl)-5-(dimethoxymethyl)-2-methylcyclohex-2-en-1-one

There total 6 articles about 4-(Benzenesulfonyl)-5-(dimethoxymethyl)-2-methylcyclohex-2-en-1-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: 72476-03-0
(E)-3-methyl-4-methoxy-2-[(trimethylsilyl)oxy]-1,3-butadiene

: 84065-67-8
3,3-dimethoxy-1-(phenylsulfonyl)propene

: 87640-83-3
5-(dimethoxymethyl)-4-(phenylsulfonyl)-2-methylcyclohex-2-enone

Guidance literature:: With hydrogenchloride; 1.) xylene, reflux, 30 h, 2.) THF, 5 h;
DOI:10.1021/jo00173a040

Reference yield: 77.0%

: 72476-03-0
(E)-3-methyl-4-methoxy-2-[(trimethylsilyl)oxy]-1,3-butadiene

: 84065-67-8
3,3-dimethoxy-1-(phenylsulfonyl)propene

: 84065-68-9,87640-83-3
(4R,5S)-4-Benzenesulfonyl-5-dimethoxymethyl-2-methyl-cyclohex-2-enone

Guidance literature:: DOI:10.1021/jo00149a035

Reference yield:

: 6044-68-4
3,3-dimethoxyprop-1-ene

: 87640-83-3
5-(dimethoxymethyl)-4-(phenylsulfonyl)-2-methylcyclohex-2-enone

Guidance literature:: Multi-step reaction with 2 steps

1: 2.) 15percent H₂O₂ / 1.) CCl₄, irradiation, 1.5 h, 2.) CH₂Cl₂, 30 min, 0 deg C then 30 min, RT

2: 77 percent / 2.) 1percent HCl / 1.) xylene, reflux, 30 h, 2.) THF, 5 h

With hydrogenchloride; dihydrogen peroxide;
DOI:10.1021/jo00173a040