(2-Phenoxyethene-1,1-diyl)bis(trimethylstannane)

Base Information

Chemical Name:(2-Phenoxyethene-1,1-diyl)bis(trimethylstannane)
CAS No.:87673-37-8
Molecular Formula:C₁₄H₂₄OSn₂
Molecular Weight:445.764
Hs Code.:
DSSTox Substance ID:DTXSID70519371

Synonyms:87673-37-8;(2-Phenoxyethene-1,1-diyl)bis(trimethylstannane);DTXSID70519371

Suppliers and Price of (2-Phenoxyethene-1,1-diyl)bis(trimethylstannane)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of (2-Phenoxyethene-1,1-diyl)bis(trimethylstannane)

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:4
Exact Mass:445.98652
Heavy Atom Count:17
Complexity:249

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[Sn](C)(C)C(=COC1=CC=CC=C1)[Sn](C)(C)C

Technology Process of (2-Phenoxyethene-1,1-diyl)bis(trimethylstannane)

There total 1 articles about (2-Phenoxyethene-1,1-diyl)bis(trimethylstannane) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1631-73-8
trimethylstannane

: 87673-33-4
1-Phenoxy-2-(trimethylstannyl)ethyn

: 87673-37-8
C₆H₅OCHC(Sn(CH₃)3)2

: (CH₃)3SnC(OC₆H₅)CHSn(CH₃)3

Guidance literature:: With catalyst: azobisisobutyronitrile; In neat (no solvent); equimolar amts. of the alkyne and Me3SnH were heated at 70°C under Ar in the presence of a catalytic amt. of AIBN for 3-4 h (IR and (1)H NMR monitoring); PhOCH=C(SnMe3)2 to PhO(Me3Sn)C=CHSnMe3 ratio 95:5, total yield 64%; the reaction mixt. was distilled under reduced pressure (b.p. 90°C/0.001 mm Hg); elem. anal. for the isomeric mixt., isomers were not sepd.;
DOI:10.1016/0022-328X(83)80057-6

Reference yield:

: 87673-37-8
C₆H₅OCHC(Sn(CH₃)3)2

: 1631-73-8
trimethylstannane

: 88151-05-7
C₆H₅OCH₂C(Sn(CH₃)3)3

Guidance literature:: With catalyst: azobisisobutyronitrile; In neat (no solvent); equimolar amts. of the alkene and Me3SnH were heated at 70°C under Ar in the presence of a catalytic amt. of AIBN for 3-4 h, reaction was monitored by IR and (1)H NMR spectroscopy; volatiles were removed by heating at 60°C and 0.001 mm Hg;
DOI:10.1016/0022-328X(83)80057-6