Vanadium,oxobis[2-[(phenylimino-kN)methyl]phenolato-kO]-

Base Information

Chemical Name:Vanadium,oxobis[2-[(phenylimino-kN)methyl]phenolato-kO]-
CAS No.:14783-75-6
Molecular Formula:C₂₆H₂₀N₂O₃V
Molecular Weight:459.398
Hs Code.:
Mol file:14783-75-6.mol

Synonyms:Vanadium,oxobis[2-[(phenylimino)methyl]phenolato-N,O]-; Vanadium,oxobis[o-(N-phenylformimidoyl)phenolato]- (7CI,8CI); Phenol,2-[(phenylimino)methyl]-, vanadium complex; NSC 162809

Suppliers and Price of Vanadium,oxobis[2-[(phenylimino-kN)methyl]phenolato-kO]-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 4 raw suppliers

Chemical Property of Vanadium,oxobis[2-[(phenylimino-kN)methyl]phenolato-kO]-

Chemical Property:

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Vanadium,oxobis[2-[(phenylimino-kN)methyl]phenolato-kO]-

There total 3 articles about Vanadium,oxobis[2-[(phenylimino-kN)methyl]phenolato-kO]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: vanadyl(IV) sulfate dihydrate

: 90-02-8
salicylaldehyde

: 62-53-3
aniline

: 14783-75-6
bis(N-phenylsalicylaldiminato)oxovanadium(IV)

Guidance literature:: In ethanol; water; addition of a solution of 0.002 mol salicylaldehyde and 0.002 mol aniline in 10 ml ethanol drop by drop under stirring to a solution of 0.005 mol VOSO4*2H2O in 20 ml water;; recrystallization from toluene;;
DOI:10.1016/0022-1902(65)80031-8

Reference yield: 80.0%

: oxovanadium(IV) sulfate

N-phenylsalicylaldimine: 779-84-0
N-phenylsalicylaldimine

: 14783-75-6
VO(C₆H₅NCHC₆H₄O)2

Guidance literature:: In ethanol; water; mixing ethanolic soln. of Schiff base and aq. vanadyl sulfate soln.; addn. of excess of water; immediate pptn.; filtration; washing (water, 50% ethanol); drying over P2O5 in vac. desiccator; elem. anal.;

Reference yield:

: vanadium(IV) chloride

: 90-02-8
salicylaldehyde

: 62-53-3
aniline

: 14783-75-6
bis(N-phenylsalicylaldiminato)oxovanadium(IV)

Guidance literature:: In ethanol; heating a solution of 0.01 mol VOCl2 (in H2O), 0.02 mol Na acetate, 0.02 mol salicylaldehyde and 0.025 mol C6H5NH2 in 50 ml ethanol;; crystallization; washing with petroleum ether and drying in vacuum;;
DOI:10.1021/ic50038a024