[(4-Bromo-3-methylbutoxy)methyl]benzene

Base Information

Chemical Name:[(4-Bromo-3-methylbutoxy)methyl]benzene
CAS No.:87974-13-8
Molecular Formula:C₁₂H₁₇BrO
Molecular Weight:257.17
Hs Code.:
DSSTox Substance ID:DTXSID10601628

Synonyms:[(4-bromo-3-methylbutoxy)methyl]benzene;87974-13-8;(4-bromo-3-methylbutoxy)methylbenzene;SCHEMBL9841232;DTXSID10601628;EN300-673872

Suppliers and Price of [(4-Bromo-3-methylbutoxy)methyl]benzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of [(4-Bromo-3-methylbutoxy)methyl]benzene

Chemical Property:

Boiling Point:298.0±23.0 °C(Predicted)
PSA：9.23000
Density:1.235±0.06 g/cm3(Predicted)
LogP:3.62430
XLogP3:3.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:6
Exact Mass:256.04628
Heavy Atom Count:14
Complexity:132

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC(CCOCC1=CC=CC=C1)CBr

Technology Process of [(4-Bromo-3-methylbutoxy)methyl]benzene

There total 3 articles about [(4-Bromo-3-methylbutoxy)methyl]benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 58558-53-5
(((3-methylbut-3-en-1-yl)oxy)methyl)benzene

: 87974-13-8
4-Bromo-3-methylbutyl benzyl ether

Guidance literature:: With sodium tetrahydroborate; boron trifluoride diethyl etherate; bromine; sodium methylate; Yield given. Multistep reaction; 1.) THF, 20 deg C, 15 min; 2.) MeOH, 20 deg C, 20 min;
DOI:10.1055/s-1983-30520

Reference yield:

: 763-32-6
2-methyl-1-buten-4-ol

: 87974-13-8
4-Bromo-3-methylbutyl benzyl ether

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) NaH / 1.) THF, reflux, 2 h; 2.) reflux, 5 h

2: 1.) NaBH₄, BF₃*Et₂O; 2.) Br₂, CH₃ONa / 1.) THF, 20 deg C, 15 min; 2.) MeOH, 20 deg C, 20 min

With sodium tetrahydroborate; boron trifluoride diethyl etherate; bromine; sodium methylate; sodium hydride;
DOI:10.1055/s-1983-30520

Reference yield:

: 100-44-7
benzyl chloride

: 87974-13-8
4-Bromo-3-methylbutyl benzyl ether

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) NaH / 1.) THF, reflux, 2 h; 2.) reflux, 5 h

2: 1.) NaBH₄, BF₃*Et₂O; 2.) Br₂, CH₃ONa / 1.) THF, 20 deg C, 15 min; 2.) MeOH, 20 deg C, 20 min

With sodium tetrahydroborate; boron trifluoride diethyl etherate; bromine; sodium methylate; sodium hydride;
DOI:10.1055/s-1983-30520