3-(2-Methylphenyl)-2H-azirene

Base Information

Chemical Name:3-(2-Methylphenyl)-2H-azirene
CAS No.:88089-30-9
Molecular Formula:C9H9N
Molecular Weight:131.177
Hs Code.:
DSSTox Substance ID:DTXSID40524275
Wikidata:Q82391017

Synonyms:3-(o-Tolyl)-2H-azirine;88089-30-9;3-(2-methylphenyl)-2H-azirine;3-(2-Methylphenyl)-2H-azirene;DTXSID40524275

Suppliers and Price of 3-(2-Methylphenyl)-2H-azirene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of 3-(2-Methylphenyl)-2H-azirene

Chemical Property:

XLogP3:1.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:1
Exact Mass:131.073499291
Heavy Atom Count:10
Complexity:160

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC=CC=C1C2=NC2

Technology Process of 3-(2-Methylphenyl)-2H-azirene

There total 6 articles about 3-(2-Methylphenyl)-2H-azirene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 90564-68-4
1-(1-azidovinyl)-2-methylbenzene

: 88089-30-9
3-(o-tolyl)-2H-azirine

Guidance literature:: at 130 ℃; for 0.266667h; under 6000.6 Torr; Green chemistry;
DOI:10.3762/BJOC.17.20

Reference yield:

: 611-15-4
1-methyl-2-vinyl-benzene

: 88089-30-9
3-(o-tolyl)-2H-azirine

Guidance literature:: Multi-step reaction with 4 steps

1: bromine / tetrachloromethane / 2 h / 15 - 20 °C

2: sodium azide / dimethyl sulfoxide / 13 h / 25 °C

3: sodium hydroxide / water / 24 h / 25 °C

4: toluene / 4 h

With sodium azide; bromine; sodium hydroxide; In tetrachloromethane; water; dimethyl sulfoxide; toluene;
DOI:10.1021/acs.orglett.6b01696

Reference yield:

: C₉H₁₀BrN₃

: 88089-30-9
3-(o-tolyl)-2H-azirine

Guidance literature:: Multi-step reaction with 2 steps

1: sodium hydroxide / water / 24 h / 25 °C

2: toluene / 4 h

With sodium hydroxide; In water; toluene;
DOI:10.1021/acs.orglett.6b01696