Lithium, [(1,1-dimethylethyl)diphenylsilyl]-

Base Information

Chemical Name:Lithium, [(1,1-dimethylethyl)diphenylsilyl]-
CAS No.:88108-89-8
Molecular Formula:C16H19LiSi
Molecular Weight:246.353
Hs Code.:
DSSTox Substance ID:DTXSID80447333

Synonyms:Lithium, [(1,1-dimethylethyl)diphenylsilyl]-;88108-89-8;DTXSID80447333

Suppliers and Price of Lithium, [(1,1-dimethylethyl)diphenylsilyl]-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Lithium, [(1,1-dimethylethyl)diphenylsilyl]-

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:2
Exact Mass:246.14160557
Heavy Atom Count:18
Complexity:204

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:[Li+].CC(C)(C)[Si-](C1=CC=CC=C1)C2=CC=CC=C2

Technology Process of Lithium, [(1,1-dimethylethyl)diphenylsilyl]-

There total 1 articles about Lithium, [(1,1-dimethylethyl)diphenylsilyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 58479-61-1
tert-butylchlorodiphenylsilane

: 88108-89-8
tert-butyldiphenylsilyl-lithium

Guidance literature:: With lithium; In tetrahydrofuran; at 0 ℃; for 96h;

Reference yield: 90.0%

: 141-79-7
4-methyl-pent-3-en-2-one

: 463-49-0
1,2-propanediene

: 88108-89-8
tert-butyldiphenylsilyl-lithium

: 383366-06-1
5-tert-butyldiphenylsilylmethyl-4,4-dimethyl-5-hexen-2-one

Guidance literature:: tert-butyldiphenylsilyl-lithium; With copper(l) cyanide; In tetrahydrofuran; at 0 ℃; for 0.5h;

1,2-propanediene; In tetrahydrofuran; at -40 ℃; for 1h;

4-methyl-pent-3-en-2-one; With boron trifluoride diethyl etherate; In tetrahydrofuran; at -78 - 0 ℃;
DOI:10.1021/jo051868g

Reference yield: 90.0%

: 463-49-0
1,2-propanediene

: 88108-89-8
tert-butyldiphenylsilyl-lithium

: 107-02-8,25068-14-8
acrolein

: 4-(tert-butyldiphenylsilylmethyl)pent-4-enal

Guidance literature:: tert-butyldiphenylsilyl-lithium; With copper(l) cyanide; In tetrahydrofuran; at 0 ℃; for 0.5h;

1,2-propanediene; In tetrahydrofuran; at -40 ℃; for 1h;

acrolein; With chloro-trimethyl-silane; In tetrahydrofuran; at -78 - 0 ℃;
DOI:10.1021/jo051868g