1,3-Tridecadiene, (Z)-

Base Information

• Chemical Name: 1,3-Tridecadiene, (Z)-
• CAS No.: 88240-21-5
• Molecular Formula: C13H24
• Molecular Weight: 180.334
• Mol file: 88240-21-5.mol

Synonyms:

Chemical Property of 1,3-Tridecadiene, (Z)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,3-Tridecadiene, (Z)-

There total 1 articles about 1,3-Tridecadiene, (Z)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

trifluorormethanesulfonic acid (1493-13-6) + Tridecadien-(1.2) (95112-45-1) + triphenylphosphine (603-35-0) → (Z)-trideca-1,3-diene (88240-21-5) + Trifluoro-methanesulfonatetriphenyl-((E)-tridec-3-enyl)-phosphonium;

Guidance literature:

With rhodium hydrido (PEt₃)3 complex; In tetrahydrofuran; at 0 ℃; for 6h;

DOI:10.1246/cl.2002.272

Reference yield:

(Z)-trideca-1,3-diene (88240-21-5) → C17H34O2

Guidance literature:

Multi-step reaction with 6 steps

1.1: phosphonite ligand; [Pt(1,5-diphenylpenta-1,4-dien-3-one)3] / tetrahydrofuran / 0.33 h / 80 °C / Inert atmosphere

1.2: 20 - 60 °C / Inert atmosphere

2.1: dichloromethane / 12 h / 20 °C / Inert atmosphere

3.1: dihydrogen peroxide; sodium hydroxide / tetrahydrofuran; dichloromethane / 0 - 20 °C / Inert atmosphere

4.1: ozone / methanol; dichloromethane / -78 °C / Inert atmosphere

5.1: sodium tetrahydroborate / 1 h / Inert atmosphere

6.1: toluene-4-sulfonic acid / 60 °C / Inert atmosphere

With sodium tetrahydroborate; [Pt(1,5-diphenylpenta-1,4-dien-3-one)3]; phosphonite ligand; dihydrogen peroxide; toluene-4-sulfonic acid; ozone; sodium hydroxide; In tetrahydrofuran; methanol; dichloromethane;

DOI:10.1002/anie.201105716

upstream raw materials:

trifluorormethanesulfonic acid

Tridecadien-(1.2)

triphenylphosphine