Benzaldehyde, 4-(tributylstannyl)-

Base Information

• Chemical Name: Benzaldehyde, 4-(tributylstannyl)-
• CAS No.: 88373-27-7
• Molecular Formula: C19H32OSn
• Molecular Weight: 395.172
• DSSTox Substance ID: DTXSID10463203
• Mol file: 88373-27-7.mol

Synonyms:88373-27-7;Benzaldehyde, 4-(tributylstannyl)-;4-tributylstannyl benzaldehyde;4-(tributylstannyl)benzaldehyde;SCHEMBL1356038;DTXSID10463203;SDKHMUMPGVDDAR-UHFFFAOYSA-N;EN300-1153663

Chemical Property of Benzaldehyde, 4-(tributylstannyl)-

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 11
• Exact Mass: 396.147518
• Heavy Atom Count: 21
• Complexity: 247

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCC[Sn](CCCC)(CCCC)C1=CC=C(C=C1)C=O

Technology Process of Benzaldehyde, 4-(tributylstannyl)-

There total 3 articles about Benzaldehyde, 4-(tributylstannyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

bis(tri-n-butyltin) (813-19-4) + 4-bromo-benzaldehyde (1122-91-4) → 4-tri-n-butylstannylbenzaldehyde (88373-27-7)

Guidance literature:

tetrakis(triphenylphosphine) palladium⁽⁰⁾; In toluene; at 23 - 100 ℃;

Reference yield: 66.0%

tributyltin chloride (1461-22-9) + 4-bromo-benzaldehyde (1122-91-4) → 4-tri-n-butylstannylbenzaldehyde (88373-27-7)

Guidance literature:

With trifluoroacetic acid; cobalt(II) bromide; zinc; In acetonitrile; CoBr2 and Zn dust activated with CF3CO2H reacted for 5 min with allyl chloride in MeCN, aryl halide and tributylstannyl chloride added simultaneously in MeCN at room temp., stirred for 1 h at 50°C;

DOI:10.1039/b417326k

Reference yield:

bis(tri-n-butyltin) (813-19-4) → 4-tri-n-butylstannylbenzaldehyde (88373-27-7)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; In 1,4-dioxane; toluene; at 100 ℃; Inert atmosphere;

DOI:10.1021/acs.joc.1c02800

upstream raw materials:

tributyltin chloride

4-bromo-benzaldehyde

bis(tri-n-butyltin)

Downstream raw materials:

4-<2-isobutyramido-9-(2,3,5-tri-O-isobutyryl-β-D-ribofuranosyl)purin-6-on-8-yl>benzaldehyde

(E)-t-butyl 4-formylcinnamate

dicarbonylcyclopentadienyl(4-formylphenyl)iron

(E)-1-bromo-3,3,3-trifluoro-1-(4-formylpheyl)-2-tosyloxypropene