13-Methylidenetricos-11-yne

Base Information

Chemical Name:13-Methylidenetricos-11-yne
CAS No.:88472-55-3
Molecular Formula:C₂₄H₄₄
Molecular Weight:332.613
Hs Code.:
DSSTox Substance ID:DTXSID00574958
Nikkaji Number:J1.703.335B
Wikidata:Q82464160

Synonyms:13-METHYLIDENETRICOS-11-YNE;88472-55-3;DTXSID00574958

Suppliers and Price of 13-Methylidenetricos-11-yne

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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Total 0 raw suppliers

Chemical Property of 13-Methylidenetricos-11-yne

Chemical Property:

XLogP3:12
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:18
Exact Mass:332.344301404
Heavy Atom Count:24
Complexity:324

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCCCCCCCCCC#CC(=C)CCCCCCCCCC

Technology Process of 13-Methylidenetricos-11-yne

There total 6 articles about 13-Methylidenetricos-11-yne which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 765-03-7
1-dodecyne

: 88472-55-3
13-methylene-11-tricosyne

Guidance literature:: With C₃₃H₄₇ClN₂Pd; tris(2,6-dimethoxyphenyl)phosphine; cesium pivalate; In toluene; at 60 ℃; for 7h; regioselective reaction; Inert atmosphere; Glovebox; Schlenk technique;
DOI:10.1002/chem.201402809

Reference yield:

: 765-03-7
1-dodecyne

: 88472-55-3
13-methylene-11-tricosyne

: (E)-11-tetracosen-13-yne

Guidance literature:: With palladium diacetate; potassium carbonate; 1,3-bis(mesityl)imidazolium chloride; In N,N-dimethyl acetamide; at 80 ℃; for 2h; Title compound not separated from byproducts.;
DOI:10.1021/jo010837s

Reference yield:

: 765-03-7
1-dodecyne

: (Z)-11-tetracosen-13-yne

: 88472-55-3
13-methylene-11-tricosyne

: (E)-11-tetracosen-13-yne

Guidance literature:: With palladium diacetate; caesium carbonate; 1,3-bis(mesityl)imidazolium chloride; In N,N-dimethyl acetamide; at 80 ℃; for 2h; Title compound not separated from byproducts.;
DOI:10.1021/jo010837s