6,6-Dimethylbicyclo[3.1.1]heptane

Base Information

• Chemical Name: 6,6-Dimethylbicyclo[3.1.1]heptane
• CAS No.: 127-92-4
• Molecular Formula: C₉H₁₆
• Molecular Weight: 124.226
• Mol file: 127-92-4.mol

Synonyms:Norpinane,6,6-dimethyl- (6CI,8CI); 6,6-Dimethylnorpinane; Apopinane

Chemical Property of 6,6-Dimethylbicyclo[3.1.1]heptane

Chemical Property:

• PSA: 0.00000
• LogP: 2.83260

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 6,6-Dimethylbicyclo[3.1.1]heptane

There total 4 articles about 6,6-Dimethylbicyclo[3.1.1]heptane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

7,7-dimethyl-2-(hydroxymethyl)bicyclo<3.1.1>heptane (514-99-8) → 6,6-Dimethyl-bicyclo<3.1.1>heptan (127-92-4)

Guidance literature:

With kieselguhr; nickel; at 160 ℃; under 44130.5 Torr; Hydrogenation;

DOI:10.1021/ja01153a014

Reference yield:

apopinene (32863-61-9) → 6,6-Dimethyl-bicyclo<3.1.1>heptan (127-92-4)

Guidance literature:

With kieselguhr; nickel; pentane; at 68 - 80 ℃; under 73550.8 Torr; Hydrogenation;

DOI:10.1021/jo01091a624

Reference yield:

→ 6,6-Dimethyl-bicyclo<3.1.1>heptan (127-92-4)

Guidance literature:

With sodium ethanolate; at 180 - 190 ℃;

upstream raw materials:

apopinene

7,7-dimethyl-2-(hydroxymethyl)bicyclo<3.1.1>heptane

cis-myrtanol

Downstream raw materials:

7-methyl-1,6-octadiene

(+/-)-cis-1-isopropenyl-2-methyl-cyclopentane