Dimethylmatairesinol

Base Information

• Chemical Name: Dimethylmatairesinol
• CAS No.: 4773-01-7
• Molecular Formula: C22H26O6
• Molecular Weight: 386.445
• NSC Number: 401390
• DSSTox Substance ID: DTXSID70963916
• Nikkaji Number: J510.164F
• Wikidata: Q82945815
• Mol file: 4773-01-7.mol

Synonyms:dimethylmatairesinol

Chemical Property of Dimethylmatairesinol

Chemical Property:

• Vapor Pressure: 5.82E-12mmHg at 25°C
• Boiling Point: 545.6°Cat760mmHg
• Flash Point: 237.2°C
• Density: 1.175g/cm³
• XLogP3: 3.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 8
• Exact Mass: 386.17293854
• Heavy Atom Count: 28
• Complexity: 497

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1=C(C=C(C=C1)CC2COC(=O)C2CC3=CC(=C(C=C3)OC)OC)OC

Technology Process of Dimethylmatairesinol

There total 52 articles about Dimethylmatairesinol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

3,4-Bis-(3,4-dimethoxy-benzyl)-5H-furan-2-one (42245-54-5) → dihydro-3,4-diveratryl-2(3H)-furanone (4773-01-7)

Guidance literature:

With hydrogen; palladium on activated charcoal; In ethanol; for 3h; under 2585.7 Torr;

DOI:10.1080/00397919209409252

Reference yield: 98.0%

(±)-secoisolariciresinol dimethyl ether (10352-25-7,58311-18-5,84893-70-9,93578-48-4,123877-50-9) → (3R*,4R*)-3-(3,4-dimethoxybenzyl)-4-(3,4-dimethoxybenzyl)-4,5-dihydro-2(3H)-furanone (4773-01-7,25488-59-9,42207-62-5,42298-56-6,81446-31-3,93451-90-2,145514-52-9)

Guidance literature:

With 1-methyl-1H-imidazole; [2,2]bipyridinyl; tetrakis(acetonitrile)copper(I) trifluoromethanesulfonate; 8-azabicyclo[3.2.1]octane-N-oxyl; In acetonitrile; at 23 ℃; for 12h;

DOI:10.1039/c9sc02682g

Reference yield: 98.0%

optically inactive 2,3-bis-(3,4-dimethoxy-benzyl)-butanediol-(1,4) (93578-48-4) → dihydro-3,4-diveratryl-2(3H)-furanone (4773-01-7)

Guidance literature:

With pyridinium chlorochromate; In dichloromethane; for 0.333333h; Ambient temperature;

upstream raw materials:

optically inactive 2,3-bis-(3,4-dimethoxy-benzyl)-butanediol-(1,4)

3,4-Bis-(3,4-dimethoxy-benzyl)-5H-furan-2-one

2,3-bis(3,4-dimethoxybenzylidene)butanedioic acid

diazomethane

Downstream raw materials:

(2R*,3S*)-2,3-(methanesulfonyloxymethyl)-1,4-bis-(3,4-dimethoxyphenyl)butane

(±)-isogalbulin

terameprocol

meso-2,3-bis[(3,4-dimethoxyphenyl)methyl]-butane-1,4-diol