Fluorosulfuric acid-d

Base Information

• Chemical Name: Fluorosulfuric acid-d
• CAS No.: 29171-24-2
• Molecular Formula: DF O3 S
• Molecular Weight: 101.063
• European Community (EC) Number: 249-485-2
• DSSTox Substance ID: DTXSID50951770
• Nikkaji Number: J250.786B
• Wikidata: Q82930198
• Mol file: 29171-24-2.mol

Synonyms:Fluorosulfuric acid-d;29171-24-2;Fluorosulphuric (2)acid;(~2~H)Sulfurofluoridic acid;DTXSID50951770;EINECS 249-485-2

Chemical Property of Fluorosulfuric acid-d

Chemical Property:

• Vapor Pressure: 0.942mmHg at 25°C
• Boiling Point: 165.5°Cat760mmHg
• Flash Point: °C
• PSA: 94.93000
• Density: 1.924g/cm³
• LogP: 4.64310
• XLogP3: -0.3
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 100.96931997
• Heavy Atom Count: 5
• Complexity: 92.6

Purity/Quality:

99% ^*data from raw suppliers

DEUTEROFLUOROSULFURIC ACID 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: OS(=O)(=O)F
• Isomeric SMILES: [2H]OS(=O)(=O)F

Technology Process of Fluorosulfuric acid-d

There total 2 articles about Fluorosulfuric acid-d which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

sulfur trioxide (7446-11-9) + hydrogen fluoride (14333-26-7) → DSO3F (29171-24-2)

Guidance literature:

In neat (no solvent); react. SO3 with DF at -30°C; distillation through short Vigreux column under vac. (bp (15 mmHg) = 85°C);

DOI:10.1039/b309362j

Reference yield:

fluorosulphonic acid (7789-21-1) + sulfuric acid-d2 (13813-19-9) → DSO3F (29171-24-2)

Guidance literature:

In not given; (N2); stirring (room temp., 24 h); distn.;

DOI:10.1021/ja962572i

Reference yield:

DSO3F (29171-24-2) + [((C6F5)2PC2H4P(C6F5)2)Pt(η2-HCCCH3)] → [((C6F5)2PC2H4P(C6F5)2)Pt(C(D)C(D)CD3)(OSO2F)]

Guidance literature:

In further solvent(s); (N2); standard Schlenk technique; Pt complex was dissolved in FSO3D at -75°C; NMR monitoring; not isolated;

DOI:10.1021/om0496838

upstream raw materials:

sulfur trioxide

hydrogen fluoride

fluorosulphonic acid

sulfuric acid-d2