Phosphorin, 2,4,6-triphenyl-

Base Information

• Chemical Name: Phosphorin, 2,4,6-triphenyl-
• CAS No.: 13497-36-4
• Molecular Formula: C23H17 P
• Molecular Weight: 324.362
• European Community (EC) Number: 603-885-7
• NSC Number: 160481
• DSSTox Substance ID: DTXSID50159173
• Nikkaji Number: J121.043B
• Wikidata: Q83027495
• Mol file: 13497-36-4.mol

Synonyms:Phosphorin, 2,4,6-triphenyl-;13497-36-4;2,4,6-Triphenylphosphinine;2,4,6-Triphenylphosphorin;PHOSPHORIN,2,4,6-TRIPHENYL-;NSC160481;Phosphorin,4,6-triphenyl-;2,4,6-triphenylphosphabenzene;2,4,6-Triphenylphosphinine #;SCHEMBL4261345;DTXSID50159173;NSC 160481;NSC-160481

Chemical Property of Phosphorin, 2,4,6-triphenyl-

Chemical Property:

• PSA: 34.14000
• LogP: 6.29160
• XLogP3: 4.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 324.106787540
• Heavy Atom Count: 24
• Complexity: 334

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C2=CC(=PC(=C2)C3=CC=CC=C3)C4=CC=CC=C4

Technology Process of Phosphorin, 2,4,6-triphenyl-

There total 7 articles about Phosphorin, 2,4,6-triphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

2,4,6-triphenylpyrylium tetrafluoroborate (448-61-3) → 2,4,6-triphenylphosphinine (13497-36-4)

Guidance literature:

With lithium bis(trimethylsilyl)phosphide; In tetrahydrofuran; for 6h; Time; Solvent; Reagent/catalyst; Inert atmosphere; Schlenk technique; Glovebox; Reflux;

DOI:10.1039/c5dt03609g

Reference yield: 25.0%

→ 2,4,6-triphenylphosphinine (13497-36-4)

Guidance literature:

With tris(hydroxymethyl)phosphine; In butan-1-ol; at 120 - 130 ℃;

Reference yield:

2,4,6-triphenylphosphinine (13497-36-4) → 2,4,6-triphenylphosphinine radical cation (13497-36-4)

Guidance literature:

2,4,6-triphenylphosphinine; With tetrakis(acetonitrile)copper(I) perchlorate; In dichloromethane; at 20 ℃;

In dichloromethane; Further stages.; beneath 20 deg C;

DOI:10.1039/b308892h

upstream raw materials:

2,4,6-triphenylpyrylium tetrafluoroborate

2,4,6-triphenylpyrilium perchlorate

2,4,6-triphenylpyrylium iodide

1,1-Dimethoxy-2,4,6-triphenyl-λ⁵-phosphorin

Downstream raw materials:

1-(1-methyl-2,4,6-triphenyl-1λ⁵-phosphinin-1-yl)-piperidine

1-Allyloxy-1-methyl-2,4,6-triphenyl-λ⁵-phosphorin

1-Methoxy-1-methyl-2,4,6-triphenyl-λ⁵-phosphorin

1-methyl-2,4,6-triphenyl-1-p-tolyloxy-1λ⁵-phosphinine