((Z)-6-methylhept-2-en-4-yl) 2-phenylmethoxyacetate

Base Information

• Chemical Name: ((Z)-6-methylhept-2-en-4-yl) 2-phenylmethoxyacetate
• CAS No.: 102616-10-4
• Molecular Formula: C17H24 O3
• Molecular Weight: 276.376
• Mol file: 102616-10-4.mol

Synonyms:((Z)-6-methylhept-2-en-4-yl) 2-phenylmethoxyacetate;102616-10-4

Chemical Property of ((Z)-6-methylhept-2-en-4-yl) 2-phenylmethoxyacetate

Chemical Property:

• Vapor Pressure: 1.07E-05mmHg at 25°C
• Boiling Point: 371°Cat760mmHg
• Flash Point: 132.6°C
• Density: 1.004g/cm³
• XLogP3: 4.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 9
• Exact Mass: 276.17254462
• Heavy Atom Count: 20
• Complexity: 291

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC=CC(CC(C)C)OC(=O)COCC1=CC=CC=C1
• Isomeric SMILES: C/C=C\C(CC(C)C)OC(=O)COCC1=CC=CC=C1

Technology Process of ((Z)-6-methylhept-2-en-4-yl) 2-phenylmethoxyacetate

There total 1 articles about ((Z)-6-methylhept-2-en-4-yl) 2-phenylmethoxyacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

Benzyloxyacetyl chloride (19810-31-2) + (Z)-6-methyl-2-hepten-4-ol (64727-70-4) → (Z)-2-methylhept-5-en-4-ol (phenylmethoxy)acetate (102616-10-4)

Guidance literature:

With pyridine; In tetrahydrofuran; at 0 ℃; for 2h;

DOI:10.1021/jo00226a032

Reference yield:

(Z)-2-methylhept-5-en-4-ol (phenylmethoxy)acetate (102616-10-4) → (E)-(2R*,3R*)-3,7-dimethyl-2-(phenylmethoxy)oct-4-enol (102616-11-5)

Guidance literature:

With lithium aluminium tetrahydride; chloro-trimethyl-silane; lithium diisopropyl amide; Yield given. Multistep reaction; 1.) THF, from 78 deg C to O deg C;

DOI:10.1021/jo00364a058

Reference yield:

(Z)-2-methylhept-5-en-4-ol (phenylmethoxy)acetate (102616-10-4) → (E)-(2R*,3R*)-3,7-dimethyl-2-(phenylmethoxy)oct-4-enal (102616-12-6)

Guidance literature:

Multi-step reaction with 2 steps

1: 1.) LDA, Me₃SiCl, 2.) LiAlH₄ / 1.) THF, from 78 deg C to O deg C

2: 98 percent / (COCl)2, DMSO

With lithium aluminium tetrahydride; chloro-trimethyl-silane; oxalyl dichloride; dimethyl sulfoxide; lithium diisopropyl amide;

DOI:10.1021/jo00364a058

upstream raw materials:

Benzyloxyacetyl chloride

(Z)-6-methyl-2-hepten-4-ol

Downstream raw materials:

(E)-(2R*,3R*)-3,7-dimethyl-2-(phenylmethoxy)oct-4-enol

(3R*,7R*)-3,7,11-trimethyldodecan-1-ol

methyl (2R*,3S*,6R*,7S*)-2,6-dihydroxy-3,7,11-trimethyldodecanoate

(E)-(2R*,3R*)-3,7-dimethyl-2-(phenylmethoxy)oct-4-enal