(2-Cyclohexylethene-1,1-diyl)bis(trimethylstannane)

Base Information

• Chemical Name: (2-Cyclohexylethene-1,1-diyl)bis(trimethylstannane)
• CAS No.: 89029-46-9
• Molecular Formula: C₁₄H₃₀Sn₂
• Molecular Weight: 435.812
• DSSTox Substance ID: DTXSID60525269
• Mol file: 89029-46-9.mol

Synonyms:89029-46-9;(2-Cyclohexylethene-1,1-diyl)bis(trimethylstannane);DTXSID60525269

Chemical Property of (2-Cyclohexylethene-1,1-diyl)bis(trimethylstannane)

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 436.03856
• Heavy Atom Count: 16
• Complexity: 231

Purity/Quality:

85.0-99.8% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Sn](C)(C)C(=CC1CCCCC1)[Sn](C)(C)C

Technology Process of (2-Cyclohexylethene-1,1-diyl)bis(trimethylstannane)

There total 1 articles about (2-Cyclohexylethene-1,1-diyl)bis(trimethylstannane) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

trimethylstannane (1631-73-8) + cyclohexylethynyl-trimethyl-stannane (97537-57-0) → C6H11CHC(Sn(CH3)3)2 (89029-46-9)

Guidance literature:

In not given; elem. anal.;

DOI:10.1016/0022-328X(85)87105-9

Reference yield: 69.0%

C6H11CHC(Sn(CH3)3)2 (89029-46-9) + methyllithium (917-54-4) → C6H11CHC(Li)Sn(CH3)3 (97537-73-0,97537-96-7) + C6H11CHC(Li)Sn(CH3)3 (97537-73-0,97537-96-7)

Guidance literature:

In further solvent(s); byproducts: Me4Sn; a soln. of distannylalkene in Me2NCH2CH2NMe2 was added dropwise under Ar to a soln. of MeLi in the same solvent at -78°C in 1:1 molar ratio, mixt. was examined by (1)H NMR spectroscopy at room temp.; only Z-isomer was formed; vinyllithium was not obtained in pure form; (1)H NMR data at room temp.;

DOI:10.1016/0022-328X(87)85002-7

Reference yield: 67.0%

C6H11CHC(Sn(CH3)3)2 (89029-46-9) → (Z)-cyclohexylCH=CISnMe3 (89029-49-2,89029-55-0)

Guidance literature:

With iodine; In chloroform; byproducts: C6H11CH=CI2; Ar-atmosphere; slow addn. of 2 equivs. I2 to Sn-compd. (-78°C), stirring (1 h, room temp.); distn. off of CHCl3 (normal pressure);

DOI:10.1016/S0022-328X(00)99294-5

upstream raw materials:

trimethylstannane

cyclohexylethynyl-trimethyl-stannane

Downstream raw materials:

((CH₂)5CH)HCC(Sn(CH₃)2Br)2

C₆H₁₁CHC(Pb(CH₃)3)2

C₆H₁₁CHC(Li)Sn(CH₃)3

C₆H₁₁CHC(Li)Sn(CH₃)3