Benzeneethanamine, a-[2-(1,3-dioxolan-2-yl)ethenyl]-a-(phenylmethyl)-, (Z)-

Base Information

Chemical Name:Benzeneethanamine, a-[2-(1,3-dioxolan-2-yl)ethenyl]-a-(phenylmethyl)-, (Z)-
CAS No.:89188-72-7
Molecular Formula:C20H23NO2
Molecular Weight:309.408
Hs Code.:

Synonyms:

Suppliers and Price of Benzeneethanamine, a-[2-(1,3-dioxolan-2-yl)ethenyl]-a-(phenylmethyl)-, (Z)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Benzeneethanamine, a-[2-(1,3-dioxolan-2-yl)ethenyl]-a-(phenylmethyl)-, (Z)-

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Benzeneethanamine, a-[2-(1,3-dioxolan-2-yl)ethenyl]-a-(phenylmethyl)-, (Z)-

There total 8 articles about Benzeneethanamine, a-[2-(1,3-dioxolan-2-yl)ethenyl]-a-(phenylmethyl)-, (Z)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 89188-71-6
(Z)-4-benzyl-4-nitro-5-phenylpent-2-enal ethylene acetal

: 89188-72-7
(Z)-4-amino-4-benzyl-4-nitro-5-phenylpent-2-enal ethylene acetal

Guidance literature:: With zinc; In acetic acid; for 1.5h; Ambient temperature;
DOI:10.1039/P19870002027

Reference yield:

: 6125-24-2
2-Phenylnitroethane

: 89188-72-7
(Z)-4-amino-4-benzyl-4-nitro-5-phenylpent-2-enal ethylene acetal

Guidance literature:: Multi-step reaction with 7 steps

1: MeNH₂*HCl, AcOK, trimethyl orthoformate / methanol / 16 h / Heating

2: NaBH₄ / dimethylsulfoxide / 1 h / 20 °C

3: 18 percent / tetra-n-butylammonium chloride, KF*2H₂O / dimethylformamide / 4 h

4: 98 percent / di-isobutylaluminium hydride / toluene / 2 h / 0 °C

5: 81 percent / MnO₂ / CH₂Cl₂ / 0.5 h

6: 79 percent / toluene-p-sulphonic acid monohydrate / benzene / 17 h / Heating

7: 96 percent / Zn powder / acetic acid / 1.5 h / Ambient temperature

With manganese(IV) oxide; potassium fluoride; sodium tetrahydroborate; diisobutylaluminum hydride; tetrabutyl-ammonium chloride; methylamine hydrochloride; potassium acetate; toluene-4-sulfonic acid; zinc; trimethyl orthoformate; In methanol; dichloromethane; acetic acid; dimethyl sulfoxide; N,N-dimethyl-formamide; toluene; benzene;
DOI:10.1039/P19870002027

Reference yield:

: 58497-32-8
(2-nitroprop-1-ene-1,3-diyl)dibenzene

: 89188-72-7
(Z)-4-amino-4-benzyl-4-nitro-5-phenylpent-2-enal ethylene acetal

Guidance literature:: Multi-step reaction with 6 steps

1: NaBH₄ / dimethylsulfoxide / 1 h / 20 °C

2: 18 percent / tetra-n-butylammonium chloride, KF*2H₂O / dimethylformamide / 4 h

3: 98 percent / di-isobutylaluminium hydride / toluene / 2 h / 0 °C

4: 81 percent / MnO₂ / CH₂Cl₂ / 0.5 h

5: 79 percent / toluene-p-sulphonic acid monohydrate / benzene / 17 h / Heating

6: 96 percent / Zn powder / acetic acid / 1.5 h / Ambient temperature

With manganese(IV) oxide; potassium fluoride; sodium tetrahydroborate; diisobutylaluminum hydride; tetrabutyl-ammonium chloride; toluene-4-sulfonic acid; zinc; In dichloromethane; acetic acid; dimethyl sulfoxide; N,N-dimethyl-formamide; toluene; benzene;
DOI:10.1039/P19870002027