(1,1-Difluoro-5-methylhexa-1,4-dien-2-yl)benzene

Base Information

Chemical Name:(1,1-Difluoro-5-methylhexa-1,4-dien-2-yl)benzene
CAS No.:89264-16-4
Molecular Formula:C13H14F2
Molecular Weight:208.251
Hs Code.:
DSSTox Substance ID:DTXSID50531238

Synonyms:(1,1-difluoro-5-methylhexa-1,4-dien-2-yl)benzene;89264-16-4;[1-(difluoromethylene)-4-methyl-3-pentenyl]benzene;DTXSID50531238

Suppliers and Price of (1,1-Difluoro-5-methylhexa-1,4-dien-2-yl)benzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 0 raw suppliers

Chemical Property of (1,1-Difluoro-5-methylhexa-1,4-dien-2-yl)benzene

Chemical Property:

XLogP3:4.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:208.10635677
Heavy Atom Count:15
Complexity:250

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=CCC(=C(F)F)C1=CC=CC=C1)C

Technology Process of (1,1-Difluoro-5-methylhexa-1,4-dien-2-yl)benzene

There total 2 articles about (1,1-Difluoro-5-methylhexa-1,4-dien-2-yl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 89264-10-8
2,2-difluoro-1-phenylethenyl diphenyl phosphate

: 870-63-3
prenyl bromide

: 89264-16-4
(1-Difluoromethylene-4-methyl-pent-3-enyl)-benzene

Guidance literature:: With copper(l) iodide; n-butyllithium; In tetrahydrofuran; at -60 ℃; for 1h;
DOI:10.1016/S0040-4039(00)94166-2

Reference yield:

: 384-67-8
2-chloro-2,2-difluoroacetophenone

: 89264-16-4
(1-Difluoromethylene-4-methyl-pent-3-enyl)-benzene

Guidance literature:: Multi-step reaction with 2 steps

1: triethylamine / tetrahydrofuran / 24 h

2: 73 percent / butyllithium, cuprous iodide / tetrahydrofuran; various solvent(s) / 1 h / -60 °C

With copper(l) iodide; n-butyllithium; triethylamine; In tetrahydrofuran;
DOI:10.1016/S0040-4039(00)94166-2