1-(1,1-Difluoropenta-1,4-dien-2-yl)-4-methylbenzene

Base Information

Chemical Name:1-(1,1-Difluoropenta-1,4-dien-2-yl)-4-methylbenzene
CAS No.:89264-18-6
Molecular Formula:C12H12F2
Molecular Weight:194.224
Hs Code.:
DSSTox Substance ID:DTXSID10531239

Synonyms:89264-18-6;1-(1,1-Difluoropenta-1,4-dien-2-yl)-4-methylbenzene;DTXSID10531239

Suppliers and Price of 1-(1,1-Difluoropenta-1,4-dien-2-yl)-4-methylbenzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1-(1,1-Difluoropenta-1,4-dien-2-yl)-4-methylbenzene

Chemical Property:

XLogP3:4.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:194.09070671
Heavy Atom Count:14
Complexity:219

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=CC=C(C=C1)C(=C(F)F)CC=C

Technology Process of 1-(1,1-Difluoropenta-1,4-dien-2-yl)-4-methylbenzene

There total 2 articles about 1-(1,1-Difluoropenta-1,4-dien-2-yl)-4-methylbenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 89264-11-9
Phosphoric acid 2,2-difluoro-1-p-tolyl-vinyl ester diphenyl ester

: 106-95-6
allyl bromide

: 89264-18-6
1-(1-Difluoromethylene-but-3-enyl)-4-methyl-benzene

Guidance literature:: With copper(l) iodide; n-butyllithium; In tetrahydrofuran; at -60 ℃; for 1h;
DOI:10.1016/S0040-4039(00)94166-2

Reference yield:

: 89264-09-5
1-(3-chloro-1,1,3,3-tetrafluoroprop-1-en-2-yl)-4-methylbenzene

: 89264-18-6
1-(1-Difluoromethylene-but-3-enyl)-4-methyl-benzene

Guidance literature:: Multi-step reaction with 2 steps

1: 85 percent / triethylamine / tetrahydrofuran / 24 h

2: 70 percent / butyllithium, cuprous iodide / tetrahydrofuran; various solvent(s) / 1 h / -60 °C

With copper(l) iodide; n-butyllithium; triethylamine; In tetrahydrofuran;
DOI:10.1016/S0040-4039(00)94166-2