[(6-Oxabicyclo[3.1.0]hexan-1-yl)methyl](oxo)diphenyl-lambda~5~-phosphane

Base Information

Chemical Name:[(6-Oxabicyclo[3.1.0]hexan-1-yl)methyl](oxo)diphenyl-lambda~5~-phosphane
CAS No.:89358-69-0
Molecular Formula:C18H19O2P
Molecular Weight:298.31600
Hs Code.:
DSSTox Substance ID:DTXSID10527197

Synonyms:89358-69-0;DTXSID10527197;[(6-Oxabicyclo[3.1.0]hexan-1-yl)methyl](oxo)diphenyl-lambda~5~-phosphane

Suppliers and Price of [(6-Oxabicyclo[3.1.0]hexan-1-yl)methyl](oxo)diphenyl-lambda~5~-phosphane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [(6-Oxabicyclo[3.1.0]hexan-1-yl)methyl](oxo)diphenyl-lambda~5~-phosphane

Chemical Property:

PSA：39.41000
LogP:3.32200
XLogP3:2.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:4
Exact Mass:298.11226684
Heavy Atom Count:21
Complexity:401

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1CC2C(C1)(O2)CP(=O)(C3=CC=CC=C3)C4=CC=CC=C4

Technology Process of [(6-Oxabicyclo[3.1.0]hexan-1-yl)methyl](oxo)diphenyl-lambda~5~-phosphane

There total 4 articles about [(6-Oxabicyclo[3.1.0]hexan-1-yl)methyl](oxo)diphenyl-lambda~5~-phosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 89358-59-8
1-(diphenylphosphinoylmethyl)cyclopentene

: 89358-69-0
1-diphenylphosphinoylmethyl-6-oxybicyclo<3.1.0>hexane

Guidance literature:: With sodium carbonate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; for 72h; Ambient temperature;

Reference yield:

: 89358-62-3
1-(diphenylphosphinoylmethyl)cyclopentanol

: 89358-69-0
1-diphenylphosphinoylmethyl-6-oxybicyclo<3.1.0>hexane

Guidance literature:: Multi-step reaction with 2 steps

1: 89 percent / TFA / 2 h / Heating

2: 92 percent / Na₂CO₃, MCPBA / CH₂Cl₂ / 72 h / Ambient temperature

With sodium carbonate; 3-chloro-benzenecarboperoxoic acid; trifluoroacetic acid; In dichloromethane;

Reference yield:

: 120-92-3
cyclopentanone

: 89358-69-0
1-diphenylphosphinoylmethyl-6-oxybicyclo<3.1.0>hexane

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) BuLi / 1.) THF, -78 deg C, 10 min, 2.) -78 deg C -> room temperature

2: 89 percent / TFA / 2 h / Heating

3: 92 percent / Na₂CO₃, MCPBA / CH₂Cl₂ / 72 h / Ambient temperature

With n-butyllithium; sodium carbonate; 3-chloro-benzenecarboperoxoic acid; trifluoroacetic acid; In dichloromethane;