Butyl(2,4,6-tri-tert-butylphenyl)phosphane

Base Information

• Chemical Name: Butyl(2,4,6-tri-tert-butylphenyl)phosphane
• CAS No.: 89566-74-5
• Molecular Formula: C₂₂H₃₉P
• Molecular Weight: 334.525
• DSSTox Substance ID: DTXSID70587116
• Wikidata: Q82479414
• Mol file: 89566-74-5.mol

Synonyms:89566-74-5;BUTYL(2,4,6-TRI-TERT-BUTYLPHENYL)PHOSPHANE;DTXSID70587116

Chemical Property of Butyl(2,4,6-tri-tert-butylphenyl)phosphane

Chemical Property:

• XLogP3: 7.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 7
• Exact Mass: 334.278938242
• Heavy Atom Count: 23
• Complexity: 326

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCPC1=C(C=C(C=C1C(C)(C)C)C(C)(C)C)C(C)(C)C

Technology Process of Butyl(2,4,6-tri-tert-butylphenyl)phosphane

There total 7 articles about Butyl(2,4,6-tri-tert-butylphenyl)phosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(2,4,6-tri-tert-butylphenyl)(trimethylsilyl)phosphane (91425-17-1) → bis(2,4,6-tri-tert-butylphenyl)diphosphene (79073-99-7) + (2,4,6-tri-tert-butylphenyl)bis(trimethylsilyl)phosphine (87174-74-1) + meso-bis(2,4,6-tri-tert-butylphenyl)diphosphene (83115-14-4) + butyl(2,4,6-tri-tert-butylphenyl)phosphine (89566-74-5)

Guidance literature:

(2,4,6-tri-tert-butylphenyl)(trimethylsilyl)phosphane; With n-butyllithium; In tetrahydrofuran; hexane; for 0.25h; Inert atmosphere;

With Bromoform; In tetrahydrofuran; hexane; at -78 - 20 ℃; Inert atmosphere;

DOI:10.3998/ark.5550190.0013.203

Reference yield:

C22H39OP + p-toluenesulfonyl chloride (98-59-9) → C29H45O3PS + butyl(2,4,6-tri-tert-butylphenyl)phosphine (89566-74-5)

Guidance literature:

C₂₂H₃₉OP; With n-butyllithium; In tetrahydrofuran; hexane; at -78 - 20 ℃;

p-toluenesulfonyl chloride; In tetrahydrofuran; hexane; for 1h;

DOI:10.1002/anie.201801427

Reference yield:

C44H76P2S (89558-13-4) → butyl(2,4,6-tri-tert-butylphenyl)phosphine (89566-74-5)

Guidance literature:

With hydrogenchloride; In benzene;

DOI:10.1246/cl.1984.115

upstream raw materials:

C₄₄H₇₆P₂S

1,2-dibutyl-1,2-bis-(2,4,6-tri-t-butylphenyl)diphosphane

C₄₀H₆₇P₂^(1-)*Li⁽¹⁺⁾

(2,4,6-tri-tert-butylphenyl)phosphine