(2R-cis)-Epoxydecenol

Base Information

Chemical Name:(2R-cis)-Epoxydecenol
CAS No.:123932-68-3
Molecular Formula:C10H20 O2
Molecular Weight:172.268
Hs Code.:
Mol file:123932-68-3.mol

Synonyms:(2R-cis)-Epoxydecenol;Oxiranemethanol, 3-heptyl-, (2R, 3S)-;123932-68-3;[(2R,3S)-3-heptyloxiran-2-yl]methanol;SCHEMBL7344379;(2R-cis)-3-heptyloxiranemethanol;MZPZDPXPQAQGJD-VHSXEESVSA-N

Suppliers and Price of (2R-cis)-Epoxydecenol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of (2R-cis)-Epoxydecenol

Chemical Property:

Vapor Pressure:0.003mmHg at 25°C
Boiling Point:252.5°Cat760mmHg
Flash Point:94.6°C
Density:0.941g/cm³
XLogP3:2.7
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:7
Exact Mass:172.146329876
Heavy Atom Count:12
Complexity:114

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCCCCCCC1C(O1)CO
Isomeric SMILES:CCCCCCC[C@H]1[C@H](O1)CO

Technology Process of (2R-cis)-Epoxydecenol

There total 4 articles about (2R-cis)-Epoxydecenol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 4194-71-2
(Z)-2-decen-1-ol

: 123932-68-3
(2R,3S)-3-heptyloxirane methanol

Guidance literature:: With titanium(IV) isopropylate; tert.-butylhydroperoxide; (-)-diethyl tartrate; In dichloromethane; at -20 ℃;
DOI:10.1016/j.tetlet.2004.07.153

Reference yield:

: 4194-71-2
(Z)-2-decen-1-ol

: 107033-43-2
[(2S,3R)-3-heptyloxiran-2-yl]methanol

: 123932-68-3
(2R,3S)-3-heptyloxirane methanol

Guidance literature:: With titanium(IV) isopropylate; tert.-butylhydroperoxide; diethyl (2R,3R)-tartrate; In dichloromethane; Yield given. Yields of byproduct given. Title compound not separated from byproducts; 4 Angstroem molecular sieves; 1.)-20 deg C, 0.5 h, 2.) -10 deg C, 29 h;
DOI:10.1021/ja00253a032

Reference yield:

: 629-04-9
1-Bromoheptane

: 123932-68-3
(2R,3S)-3-heptyloxirane methanol

Guidance literature:: Multi-step reaction with 3 steps

1.1: n-butyllithium / hexane; tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide / 3 h / -78 - -30 °C / Inert atmosphere; Schlenk technique

1.2: -30 - 20 °C / Inert atmosphere; Schlenk technique

2.1: hydrogen; pyridine / ethanol / 1 h / 20 °C / Schlenk technique

3.1: titanium(IV) isopropylate; D-(-)-diisopropyl tartrate; tert.-butylhydroperoxide / dichloromethane; water; decane / 72 h / -23 - -10 °C / Molecular sieve; Inert atmosphere; Schlenk technique

With pyridine; titanium(IV) isopropylate; tert.-butylhydroperoxide; n-butyllithium; hydrogen; D-(-)-diisopropyl tartrate; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; decane; ethanol; hexane; dichloromethane; water; 3.1: |Sharpless Asymmetric Epoxidation;
DOI:10.1016/j.tetasy.2015.12.001