(E)-N-tert-Butyl-1-[2-(phenylselanyl)pyrrolidin-1-yl]methanimine

Base Information

Chemical Name:(E)-N-tert-Butyl-1-[2-(phenylselanyl)pyrrolidin-1-yl]methanimine
CAS No.:89656-34-8
Molecular Formula:C15H22N2Se
Molecular Weight:309.313
Hs Code.:
DSSTox Substance ID:DTXSID50534628

Synonyms:89656-34-8;DTXSID50534628;(E)-N-tert-Butyl-1-[2-(phenylselanyl)pyrrolidin-1-yl]methanimine

Suppliers and Price of (E)-N-tert-Butyl-1-[2-(phenylselanyl)pyrrolidin-1-yl]methanimine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (E)-N-tert-Butyl-1-[2-(phenylselanyl)pyrrolidin-1-yl]methanimine

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:4
Exact Mass:310.09482
Heavy Atom Count:18
Complexity:277

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC(C)(C)N=CN1CCCC1[Se]C2=CC=CC=C2

Technology Process of (E)-N-tert-Butyl-1-[2-(phenylselanyl)pyrrolidin-1-yl]methanimine

There total 2 articles about (E)-N-tert-Butyl-1-[2-(phenylselanyl)pyrrolidin-1-yl]methanimine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 119044-70-1
(E)-N′-tert-butyl-N,N-dimethylformimidamide

: 89656-34-8
tert-Butyl-[1-(2-phenylselanyl-pyrrolidin-1-yl)-meth-(E)-ylidene]-amine

Guidance literature:: Multi-step reaction with 2 steps

1: 92 percent / (NH₄)2SO₄ / toluene / Heating

2: 1.) t-BuLi / 1.) THF, -20 deg C, 1 h; 2.) THF, -78 -> 0 deg C, 3 h

With ammonium sulfate; tert.-butyl lithium; In toluene;
DOI:10.1021/ja00323a035

Reference yield:

: 1666-13-3
diphenyl diselenide

: 85152-51-8
1-<(tert-butyl)formimidoyl>pyrrolidine

: 89656-34-8
tert-Butyl-[1-(2-phenylselanyl-pyrrolidin-1-yl)-meth-(E)-ylidene]-amine

Guidance literature:: With tert.-butyl lithium; Multistep reaction; 1.) THF, from -78 deg C to -20 deg C, 1 h, 2.) -78 deg C, 1 h;
DOI:10.1021/jo00207a023

Reference yield:

: 89656-34-8
tert-Butyl-[1-(2-phenylselanyl-pyrrolidin-1-yl)-meth-(E)-ylidene]-amine

: tert-Butyl-[1-(5-methyl-2-phenylselanyl-2,3-dihydro-pyrrol-1-yl)-meth-(E)-ylidene]-amine

Guidance literature:: Multi-step reaction with 3 steps

1: KHCO₃, Na₂SO₄ / 24 h

2: 1.) n-BuLi / 1.) THF, from -78 deg C to -20 deg C, 1 h, 2.) from -78 deg C to 0 deg C

3: 1.) t-BuLi / 1.) ether, THF, from -78 deg C to -20 deg C, 1 h, 2.) -78 deg C, 1 h

With n-butyllithium; tert.-butyl lithium; potassium hydrogencarbonate; sodium sulfate;
DOI:10.1021/jo00207a023