9,11-Tridecadien-5-ynoic acid, 8-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-13-hydroxy-, methyl ester, (E,Z)-

Base Information

Chemical Name:9,11-Tridecadien-5-ynoic acid, 8-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-13-hydroxy-, methyl ester, (E,Z)-
CAS No.:89682-56-4
Molecular Formula:C30H38O4Si
Molecular Weight:490.715
Hs Code.:

Synonyms:

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Chemical Property of 9,11-Tridecadien-5-ynoic acid, 8-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-13-hydroxy-, methyl ester, (E,Z)-

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 9,11-Tridecadien-5-ynoic acid, 8-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-13-hydroxy-, methyl ester, (E,Z)-

There total 9 articles about 9,11-Tridecadien-5-ynoic acid, 8-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-13-hydroxy-, methyl ester, (E,Z)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 85924-38-5
8-hydroxy-oct-5-ynoic acid methyl ester

: 89682-56-4
(9E,11E)-8-(tert-Butyl-diphenyl-silanyloxy)-13-hydroxy-trideca-9,11-dien-5-ynoic acid methyl ester

Guidance literature:: Multi-step reaction with 8 steps

1: 8N Jones reagent / 0 °C

2: oxalylchloride/DMF, 1drop / benzene / 1 h

3: 16 h / 0 °C

4: 2 / 2 h / Ambient temperature

5: 60 percent / NaBH₄/CeCl₃ / propan-2-ol; H₂O / 0 °C

6: pyridine / -10 °C

7: imidazole / dimethylformamide / 0 °C

8: 80percent AcOH / tetrahydrofuran; H₂O

With 1H-imidazole; sodium tetrahydroborate; jones reagent; cerium(III) chloride; Chloro-oxo-acetic acid; acetic acid; N,N-dimethyl-formamide; dirhodium tetraacetate; In tetrahydrofuran; pyridine; water; N,N-dimethyl-formamide; isopropyl alcohol; benzene;
DOI:10.1016/S0040-4039(01)91141-4

Reference yield:

: 89682-50-8
Oct-3-ynedioic acid 8-methyl ester

: 89682-56-4
(9E,11E)-8-(tert-Butyl-diphenyl-silanyloxy)-13-hydroxy-trideca-9,11-dien-5-ynoic acid methyl ester

Guidance literature:: Multi-step reaction with 7 steps

1: oxalylchloride/DMF, 1drop / benzene / 1 h

2: 16 h / 0 °C

3: 2 / 2 h / Ambient temperature

4: 60 percent / NaBH₄/CeCl₃ / propan-2-ol; H₂O / 0 °C

5: pyridine / -10 °C

6: imidazole / dimethylformamide / 0 °C

7: 80percent AcOH / tetrahydrofuran; H₂O

With 1H-imidazole; sodium tetrahydroborate; cerium(III) chloride; Chloro-oxo-acetic acid; acetic acid; N,N-dimethyl-formamide; dirhodium tetraacetate; In tetrahydrofuran; pyridine; water; N,N-dimethyl-formamide; isopropyl alcohol; benzene;
DOI:10.1016/S0040-4039(01)91141-4

Reference yield:

: 89682-51-9
7-Chlorocarbonyl-hept-5-ynoic acid methyl ester

: 89682-56-4
(9E,11E)-8-(tert-Butyl-diphenyl-silanyloxy)-13-hydroxy-trideca-9,11-dien-5-ynoic acid methyl ester

Guidance literature:: Multi-step reaction with 6 steps

1: 16 h / 0 °C

2: 2 / 2 h / Ambient temperature

3: 60 percent / NaBH₄/CeCl₃ / propan-2-ol; H₂O / 0 °C

4: pyridine / -10 °C

5: imidazole / dimethylformamide / 0 °C

6: 80percent AcOH / tetrahydrofuran; H₂O

With 1H-imidazole; sodium tetrahydroborate; cerium(III) chloride; acetic acid; dirhodium tetraacetate; In tetrahydrofuran; pyridine; water; N,N-dimethyl-formamide; isopropyl alcohol;
DOI:10.1016/S0040-4039(01)91141-4