2-(2,2,2-Trifluoro-1-phenylethylidene)-1,3-dithiane

Base Information

Chemical Name:2-(2,2,2-Trifluoro-1-phenylethylidene)-1,3-dithiane
CAS No.:89863-73-0
Molecular Formula:C12H11F3S2
Molecular Weight:276.347
Hs Code.:
DSSTox Substance ID:DTXSID90535735
Nikkaji Number:J494.818A

Synonyms:2-(2,2,2-Trifluoro-1-phenylethylidene)-1,3-dithiane;89863-73-0;SCHEMBL10368837;DTXSID90535735;ZPAWLVSBFOXBRZ-UHFFFAOYSA-N

Suppliers and Price of 2-(2,2,2-Trifluoro-1-phenylethylidene)-1,3-dithiane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2-(2,2,2-Trifluoro-1-phenylethylidene)-1,3-dithiane

Chemical Property:

XLogP3:4.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:1
Exact Mass:276.02542718
Heavy Atom Count:17
Complexity:283

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1CSC(=C(C2=CC=CC=C2)C(F)(F)F)SC1

Technology Process of 2-(2,2,2-Trifluoro-1-phenylethylidene)-1,3-dithiane

There total 3 articles about 2-(2,2,2-Trifluoro-1-phenylethylidene)-1,3-dithiane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 434-45-7
2,2,2-Trifluoroacetophenone

: 13411-46-6
2,2-bis(trimethylsilyl)-1,3-dithiane

: 89863-73-0
2-(2,2,2-trifluoro-1-phenylethylidene)-1,3-dithiane

Guidance literature:: With cesium fluoride; In N,N-dimethyl-formamide; at 80 ℃; for 3h; Inert atmosphere; Molecular sieve;
DOI:10.1002/ejoc.201501185

Reference yield:

: 13411-42-2
2-(trimethylsilyl)-1,3-dithiane

: 434-45-7
2,2,2-Trifluoroacetophenone

: 89863-73-0
2-(2,2,2-trifluoro-1-phenylethylidene)-1,3-dithiane

Guidance literature:: With n-butyllithium; Yield given. Multistep reaction; 1) Et₂O, 0 deg C, 45 min, 2) Et₂O, 0 deg C, 2 to 3 h;
DOI:10.1055/s-1992-26280