Technology Process of Gold, (phenylethynyl)(trimethylphosphine)-
There total 7 articles about Gold, (phenylethynyl)(trimethylphosphine)- which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
methanol; sodium methylate;
at 20 ℃;
for 16h;
- Guidance literature:
-
With
water;
In
tetrahydrofuran;
byproducts: LiCl; soln. PhCCLi in THF at -78°C was added dropwise to suspn. (Ph3P)AuCl in THF, allowed to warm to room temp. and stirred for 1 h, water wasadded; solvents were evapd. in vacuo, residue was dissolved in CH2Cl2 and extd.with water, org. phase was dried over MgSO4, n-pentane was added; elem. anal.;
DOI:10.1016/j.ica.2004.07.005
- Guidance literature:
-
copper(l) chloride;
In
diethylamine;
under N2, 0.08 equiv of CuCl was added to stirred mixt. of Au-complex and ligand (molar ratio 1:1) in Et2NH, 30 min; solvent removed in vac. at room temp., water added, extd. with benzene,extract dried over MgSO4 overnight, evapd., washed with dry Et2O, recrystd. from toluene-n-octane; elem. anal.;
