1-Iodopentane

Base Information

• Chemical Name: 1-Iodopentane
• CAS No.: 628-17-1
• Molecular Formula: C5H11I
• Molecular Weight: 198.047
• Hs Code.: 29033080
• European Community (EC) Number: 211-030-0
• NSC Number: 7901
• UNII: GQ3RVU6PSC
• DSSTox Substance ID: DTXSID1060849
• Nikkaji Number: J6.876D
• Wikidata: Q25384953
• Mol file: 628-17-1.mol

Synonyms:1-IODOPENTANE;628-17-1;n-Amyl iodide;Amyl iodide;n-Pentyl iodide;Pentyl iodide;Pentane, 1-iodo-;1-Pentyl iodide;1-Jodpentan;1-Jodpentan [Czech];1-iodo-pentane;NSC 7901;GQ3RVU6PSC;EINECS 211-030-0;NSC-7901;MFCD00001100;iodopentane;pentyliodide;Amyljodid;n-pentyliodide;n-AmylIodide;1-iodanylpentane;Iodopentane, 1-;1-Iodopentane over Cu;1-Iodopentane, 98%;UNII-GQ3RVU6PSC;n-C5H11I;SCHEMBL30324;n-Amyl iodide, Pentyl iodide;SCHEMBL7991245;DTXSID1060849;BLXSFCHWMBESKV-UHFFFAOYSA-;NSC7901;STL264207;AKOS009031619;AS-17294;1-Iodopentane, purum, >=98.0% (GC);LS-101731;FT-0607970;I0066;EN300-19416;D91072;A834015;J-802039;J-802261;F0001-1690

Chemical Property of 1-Iodopentane

Chemical Property:

• Appearance/Colour: Clear colourless liquid
• Vapor Pressure: 3.65mmHg at 25°C
• Melting Point: -86 °C
• Refractive Index: n20/D 1.495(lit.)
• Boiling Point: 156.9 °C at 760 mmHg
• Flash Point: 51.1 °C
• PSA: 0.00000
• Density: 1.524 g/cm³
• LogP: 2.61160
• Storage Temp.: Flammables area
• Sensitive.: Light Sensitive
• Water Solubility.: Insoluble in water.
• XLogP3: 3.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 197.99055
• Heavy Atom Count: 6
• Complexity: 19.9

Purity/Quality:

99% ^*data from raw suppliers

1-Iodopentane ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 10-36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Other Classes -> Halogenated Aliphatics, Saturated
• Canonical SMILES: CCCCCI
• Uses: 1-Iodopentane (pentyl iodide) was used in the preparation of 1-pentyl radical by shock heating process.

Technology Process of 1-Iodopentane

There total 37 articles about 1-Iodopentane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

Tributyl-amine; compound with pentane-1-thiol → amyl iodide (628-17-1)

Guidance literature:

With (C₄H₉)3N; iodine; triphenylphosphine; In benzene; for 0.333333h; Ambient temperature;

DOI:10.1055/s-1981-29453

Reference yield: 100.0%

Tributyl-amine; compound with pentane-1-sulfinic acid → amyl iodide (628-17-1)

Guidance literature:

With (C₄H₉)3N; iodine; triphenylphosphine; In benzene; for 0.166667h; Ambient temperature;

DOI:10.1055/s-1981-29453

Reference yield: 96.0%

pentyl benzenesulfonate (80-45-5) → amyl iodide (628-17-1) + thiophenol (108-98-5)

Guidance literature:

With iodine; triphenylphosphine; In benzene; for 0.166667h; Heating;

DOI:10.1246/bcsj.56.3802

upstream raw materials:

1-Chloropentane

pentan-1-ol

1-Bromopentane

1-ethoxypentane

Downstream raw materials:

ethyl 2-(3,4,5-trimethoxybenzoyl)heptanoate

pentylbenzene

tetrapentylammonium iodide

2,4-dibromo-1-pentyloxybenzene

Refernces

The reactivity of 2,2'-bipyridine complexes in the electrochemical reduction of organohalides

10.1023/A:1016024531639

The research aimed to investigate the reactivity of nickel(0) complexes coordinated with 2,2'-bipyridine (bpy) in the electrochemical reduction of organic halides. The study focused on understanding the mechanism of the catalytic process and identifying the intermediates formed during the reduction. The researchers used nickel complexes with varying numbers of bpy ligands and different organic halides, including alkyl and aryl halides such as propyl iodide, amyl iodide, phenyl bromide, and mesityl bromide. The experiments involved electrochemical techniques like cyclic voltammetry and preparative electrolysis. The study concluded that nickel(0) complexes with fewer bpy ligands were more reactive in the oxidative addition to organic halides, leading to the formation of σ-organonickel intermediates.