1-Iodopentane

Base Information

• Chemical Name: 1-Iodopentane
• CAS No.: 628-17-1
• Molecular Formula: C5H11I
• Molecular Weight: 198.047
• Hs Code.: 29033080
• European Community (EC) Number: 211-030-0
• NSC Number: 7901
• UNII: GQ3RVU6PSC
• DSSTox Substance ID: DTXSID1060849
• Nikkaji Number: J6.876D
• Wikidata: Q25384953
• Mol file: 628-17-1.mol

Synonyms:1-IODOPENTANE;628-17-1;n-Amyl iodide;Amyl iodide;n-Pentyl iodide;Pentyl iodide;Pentane, 1-iodo-;1-Pentyl iodide;1-Jodpentan;1-Jodpentan [Czech];1-iodo-pentane;NSC 7901;GQ3RVU6PSC;EINECS 211-030-0;NSC-7901;MFCD00001100;iodopentane;pentyliodide;Amyljodid;n-pentyliodide;n-AmylIodide;1-iodanylpentane;Iodopentane, 1-;1-Iodopentane over Cu;1-Iodopentane, 98%;UNII-GQ3RVU6PSC;n-C5H11I;SCHEMBL30324;n-Amyl iodide, Pentyl iodide;SCHEMBL7991245;DTXSID1060849;BLXSFCHWMBESKV-UHFFFAOYSA-;NSC7901;STL264207;AKOS009031619;AS-17294;1-Iodopentane, purum, >=98.0% (GC);LS-101731;FT-0607970;I0066;EN300-19416;D91072;A834015;J-802039;J-802261;F0001-1690

Chemical Property of 1-Iodopentane

Chemical Property:

• Appearance/Colour: Clear colourless liquid
• Vapor Pressure: 3.65mmHg at 25°C
• Melting Point: -86 °C
• Refractive Index: n20/D 1.495(lit.)
• Boiling Point: 156.9 °C at 760 mmHg
• Flash Point: 51.1 °C
• PSA: 0.00000
• Density: 1.524 g/cm³
• LogP: 2.61160
• Storage Temp.: Flammables area
• Sensitive.: Light Sensitive
• Water Solubility.: Insoluble in water.
• XLogP3: 3.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 197.99055
• Heavy Atom Count: 6
• Complexity: 19.9

Purity/Quality:

99% ^*data from raw suppliers

1-Iodopentane ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 10-36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Other Classes -> Halogenated Aliphatics, Saturated
• Canonical SMILES: CCCCCI
• Uses: 1-Iodopentane (pentyl iodide) was used in the preparation of 1-pentyl radical by shock heating process.

Technology Process of 1-Iodopentane

There total 37 articles about 1-Iodopentane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

Tributyl-amine; compound with pentane-1-thiol → amyl iodide (628-17-1)

Guidance literature:

With (C₄H₉)3N; iodine; triphenylphosphine; In benzene; for 0.333333h; Ambient temperature;

DOI:10.1055/s-1981-29453

Reference yield: 100.0%

Tributyl-amine; compound with pentane-1-sulfinic acid → amyl iodide (628-17-1)

Guidance literature:

With (C₄H₉)3N; iodine; triphenylphosphine; In benzene; for 0.166667h; Ambient temperature;

DOI:10.1055/s-1981-29453

Reference yield: 96.0%

pentyl benzenesulfonate (80-45-5) → amyl iodide (628-17-1) + thiophenol (108-98-5)

Guidance literature:

With iodine; triphenylphosphine; In benzene; for 0.166667h; Heating;

DOI:10.1246/bcsj.56.3802

upstream raw materials:

1-Chloropentane

pentan-1-ol

1-Bromopentane

1-ethoxypentane

Downstream raw materials:

ethyl 2-(3,4,5-trimethoxybenzoyl)heptanoate

pentylbenzene

1-nitro-4-(pentyloxy)benzene

tetrapentylammonium iodide

Refernces

• 1、 Munyemana, Fran?ois,George, Isabelle,Devos, Alain,Colens, Alain,Badarau, Eduard,Frisque-Hesbain, Anne-Marie,Loudet, Aurore,Differding, Edmond,Damien, Jean-Marie,Rémion, Jeanine,Van Uytbergen, Jacqueline,Ghosez, Léon. "A mild method for the replacement of a hydroxyl group by halogen. 1. Scope and chemoselectivity". . p. 420 - 430. Retrieved 2015/12/31.
• 2、 Ranu, Brindaban C.,Jana, Ranjan. "Direct halogenation of alcohols and their derivatives with tert-Butyl halides in the ionic liquid [pmIm]Br under sonication conditions - A novel, efficient and green methodology". . p. 755 - 758. Retrieved 2007/10/03.